I guess another example is that you can build the classifying space of a discrete group G as the geometric realization of the bar construction B(*, G, *), a simplicial set. (This is in May's Concise Course, though maybe not in quite these words). But if G is a topological group (in geometry, the classifying spaces one cares about are usually for compact Lie groups), this construction doesn't quite work, and you have to take the bar construction B(*, G, *) as a simplicial space.