@Peter: a commutative, cocommutative Hopf algebra describes a group in two senses. first, the multiplication describes a group object in cocommutative coalgebras. second, the comultiplication describes a group object in (commutative algebras)^{op}. it's in this latter sense that commutative Hopf algebras can be thought of as affine group schemes. this correspondence is contravariant.
cocommutative Hopf algebras, on the other hand, should be thought of as formal groups, and this correspondence is covariant. and hopf algebras which are neither commutative nor cocommutative are just some biza…