@Jayadithya Oh then that will be in correspondence to NCERT as JEE Mains Chemistry Paper setters refer that book. Infact I just checked, NCERT has mentioned Cs and K as the only 2 to be used as electrodes in photoelectric cells. If you are targetting for advance as well with further 2 attempts of Mains then discard Rb from the list. Follow NCERT as much as possible for Mains Chem.
ncert.nic.in/ncerts/l/kech203.pdf 3rd page just bellow the big table.