When we have an atom with one electron. We excite it with a laser once and than measure the energy.
The result will be one of the eigenvalues of $\hat H$. Say it is the first excited state.
If the system is isolated (in theory) all further measurments will be the same.
In real life when we have the same setup, further measurements may not be the same. After what time will the measurments begin to differ for say a system 1.) that is not isolated, and for a 2.) system that has the best isolation that is known?