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So I'm watching the Flash series
It's painful to see Holliwood trying to do science
@Danu Mmmm ... yes. I got the wrong name. I mean Goodstein's "States of Matter"
I'll see if I can run down the quote.
01:00
0
Q: The practice of answering a question in its comments area

Physics FootnotesI've noticed that some members provide a perfectly good answer to a perfectly good question in the comments area under the question rather than posting their response as a standalone answer. As this practice often occurs among members of high standing in the community, it seems to be acceptable...

I wonder what fields are the least represented in mad science
Metrology perhaps
HE HAS MEASURED WHAT MAN WASN'T MEANT TO MEASURE
3
01:38
aeroports are boring
flights are even more boring
at least on long distance you can watch movies
 
1 hour later…
02:50
america-based regulars are rather silent today...they should still be awake
@yuggib I'm on a trip
\o
you came as summoned...good
;-P
@0celo7 me too...a long one
and boring
5 hours into it, and I've not yet completed a fourth of it
T__T
I have to board my plane...see ya in roughly 12 hours
 
1 hour later…
vzn
vzn
04:42
@Slereah by "mad science" are you referring to hollywood depictions?
 
1 hour later…
05:57
@DanielSank sleep
06:18
0
A: Gauge redundancies and global symmetries

DanuAnswer posted by Lubos Motl in the comments; I reproduce most of it here. This answer was posted in order to remove this question from the "unanswered" list. Some (sketches of) answers to your questions, one by one: Physical states have to be invariant under gauge symmetries, so all of them ar...

^let's get this off the "unanswered" list.
 
2 hours later…
user116211
08:01
17
Q: Gauge redundancies and global symmetries

NewmanIt is often said that local (gauge) transformation is only redundancy of description of spin one massless particles, to make the number degrees of freedom from three to two. It is often said that these are not really symmetries because it means that there are only apparently different points in c...

user116211
Is it 'too broad'?
09:27
@vzn mad science needs a mad scientist :P
10:26
@JohnRennie Braking a train from 300 km/h to zero in about 2.8 km braking distance:
You can also see the three different braking systems (electric motors, eddy current brakes, and disc brakes).
 
1 hour later…
11:42
@MAFIA36790 it's asking 8 questions.
user116211
Ah! got the answer, @Danu.
12:48
@ACuriousMind bist du around?
@0celo7 sort of
https://www.amazon.com/General-Relativity-Introduction-Theory-Gravitational/dp/0521379415

Is this the stephani book that slereah uses?
what is the name of that stephani book?
@ACuriousMind I'm confused by something on page 56 of Milnor. What does he mean by "locally a diffeomorphism" and why must therefore the segments of the graph end on the boundary?
Actually I'm also not sure why that composition exists on the entirety of the intervals
Maybe it doesn't
I just feel like it should only be defined on some open set of I
13:01
http://www.goodreads.com/author/show/250289.Hans_Stephani

there are at least 4 books by stepani, which one corresponds to
Aug 16 '15 at 18:10, by Slereah
It's in the Stephani book
@0celo7 ?
@0celo7 It doesn't, it exists only on (the respective preimages of) $f(I)\cap g(J)$.
and you can omit the "locally" there, it's just a diffeomorphism.
@ACuriousMind but why does it have to extend to the boundary
And actually why is it made of at most two segments, why can't it be many smaller segments with that slope
@Secret check my GR book list
ok
book found, thanks
@0celo7 If we write $I=[a,b]$, $J = [c,d]$, then "extend to the boundary" means that at least two of the four points $f(a),f(b),g(c),g(d)$ lie in $f(I)\cap g(J)$.
@0celo7 That he already explains - because $g^{-1}\circ f$ is one-to-one; $\Gamma$ having more than two components would mean it hits one of the boundaries more than once, contradicting the bijectiveness of $g^{-1}\circ f$.
13:19
@ACuriousMind but why
@ACuriousMind uh, no?
In the picture, slice one interval in half
Why isn't this allowed?
@0celo7 Okay, let's do this in small steps:
1. $\Gamma$ is diffeomorphic to $f(I)\cap g(J)$, yes?
Sure
(Taking a shower, brb)
2. Let $X:= f(I)\cap g(J)$. $g^{-1}\circ f : f^{-1}(X)\to g^{-1}(X)$ is a diffeomorphism, mapping a relatively open subset $K:=f^{-1}(X)\subset I$ to a relatively open subset $L:=g^{-1}(X)\subset J$.
13:43
Ugh, I see what the argument is, but I have a hard time verbalizing it any more precise than Milnor did
Ah: If one connected component of $\Gamma$ ended somewhere before the boundary, that would mean there is an $x\in I^o$ such that $x\in K$ and $x+\epsilon\neq K$ for all $\epsilon > 0$.
What is $I^o$ @ACuriousMind
But that would mean that one connected component of $K$ looked like $(...,x]$ for $x\in I^o$, so it could not be relatively open in $I$
@0celo7 interior of $I$ (relative to $\mathbb{R}$, I just mean to say it's a point not in the boundary)
So all connected components of $\Gamma$ have to end on the boundary, and then bijectivity of $g^{-1}\circ f$ means that there are at most two.
Not sure if that's more understandable than what Milnor wrote :P
@ACuriousMind Oh, you mean $I^\circ$
@0celo7 ::squints very hard:: Yeah.
@ACuriousMind to me $I^o$ means the identity connected component
I've been reading too much about Lie groups...
@ACuriousMind I'm not sure what this means
Why is "relatively open subset" important
Milnor says that too
@ACuriousMind I still don't get it
13:59
@0celo7 We don't know whether $I$ is closed or open, so we don't know whether there are relatively open subsets of the form $[a,b)$ where $a\in \partial I$.
But we do know that no subset of that form can be open if $a\in I^\circ$, regardless of the form of $I$
@0celo7 Why all connected components have to end on the boundary, or why that means there are at most two?
@ACuriousMind the first part
@ACuriousMind hmm, what?
oh, relatively open wrt. $\Bbb R$
@ACuriousMind ok I understand this
@ACuriousMind what
I don't understand what the local diff property of $g^{-1}\circ f$ has to do with this
@ACuriousMind and what does this have to do with anything?
sorry for being dumb :/
As I said, I have trouble verbalizing the argument any better than Milnor did :P
Milnor doesn't verbalize it well at all
I have no clue what he's talking about
@0celo7 I do not dispute that :D
@ACuriousMind well you're able to get it
somehow
14:07
Let me try on last time. Each connected component of $\Gamma$ must map to an open subset of $I$ as well as $J$.
Yes.
(maybe)
Ahhhh, why?
The connected components of $\Gamma$ look, a priori, like $\{ (x,y) \mid x\in |i_0,i_1 |\subset I, y\in |j_0,j_1|\subset J\}$ where by $|i_0,i_1|$ I mean that we are as of yet agnostic whether these are open or closed intervals.
@0celo7 Because $\Gamma$ is diffeomorphic to $f(I) \cap g(J)$, which as an open usbset of $M$ maps to open subsets $I$ and $J$ under $f^{-1}$ and $g^{-1}$, respectively.
Now you must convince yourself that a closed subset of $I\times J$ consisting of straight lines must have the $\lvert i_0,i_1\rvert$ up there as $[i_0,i_1]$ for its connected component unless $i_0$ or $i_1$ is on the boundary (then $($ instead of $[$ i permitted if $I$ resp. $J$ are open intervals).
@ACuriousMind I've never heard agnostic used that way.
@ACuriousMind I don't know how to convince myself of that...
And I fucked up, we must add $f(x)=g(y)$ to the condition ont he connected components up there
@0celo7 I have convinced myself using the sequential characterization of closedness/openness (as well as continuity of $f$ and $g$)
Sequential characterization?
like $A$ is closed iff it contains its limit points?
14:14
Yes, that one
dunno what the sequential characterization for openness is
That the complement is closed ;P
lol
ok I'll think about it
Does the fundamental theorem of calculus hold for path integrals?
Does $$\int \frac{\delta f[\phi]}{\delta \phi} d\mu[\phi] = f[\phi_b] - f[\phi_a]$$
@Slereah That doesn't make sense. $\delta f[\phi]/(\delta\phi)$ is not a functional itself, it is a function.
You can't integrate it against $\mathrm{d}\mu[\phi]$.
14:24
@Slereah Pretty sure that's used to derive Ward-Takahashi
or something similar at least
Actually, given some contnuity assumptions, the fundemental theorem of calculus generalise to path integrals
(Theorem 7 in this open access paper)
@0celo7 Not in the derivation I know
I've never seen any physicist write boundary conditions for a path integral over fields at all :P
Well then obviously you haven't read Weinberg
Or Rovelli
14:28
That's largely correct
I have read a bit of Weinberg until I decided I don't have the patience to decode that notation of his :P
yeah Weinberg is a bit of a slog to go through
And obviously you haven't read the question on SE where I asked about it
A kind soul answered it
(It was me)
@Slereah I know that you've been going on about boundaries of path integrals for a while ("any physicist...at all" was hyperbole :P)
I just want to compute quantities with it, is it so much to ask
and apparently you totally can for the free field
But the fact remains that the functional derivative is itself not a functional, you cannot integrate it against a measure on functionals, so the l.h.s. of your proposed theorem is really not defined
I suppose so yeah
Wondering if there is some kind of equivalent, though
14:35
Actually, I don't know what is time slicing approximation, thus I am not sure if my answer is actually responding to the correct context
vzn
vzn
14:54
@ACuriousMind no I mean like
$$\int\frac{\delta S}{\delta X}\,DX=0$$
I've seen that
guaranteed
@ACuriousMind can you please explain this
this argument is just too confusing
@0celo7 : That's in the proof for the Dyson equation
@0celo7 Ah, that does...kind of appear. What you actually derive is $\int \int \left(\frac{\delta S}{\delta \phi}(y)\Delta\phi(y)\right)\mathrm{d}^4 y \mathrm{e}^{\mathrm{i}S[\phi]} \mathcal{D}\phi$ and when you set $\Delta \phi(y) = \delta(x-y)$ you get Dyson-Schwinger
I don't know what that is @ACuriousMind
"Dyson-Schwinger"
Never heard of it
That is only the most important QFT equation
15:09
is it in Weinberg?
But Ward-Takahashi wasn't far off - choosing $\Delta\phi$ to be the change under a symmetry, you get the W-T identity for that symmetry
yeah
@ACuriousMind ok I don't care about physics, can you please elaborate on the Milnor proof :(
@0celo7 I said "convince yourself" because it's another argument that I see but don't really know how to clearly explain in words
But I'll try
15:11
I don't see it...
After cross checking this with acuriousmind's, 0celo7 and the paper I found, in order to have some form of "fundemental theorem of calculus" defined, you need a functional in the integrand. The expression you showed above does not have a functional, thus Theorem 7 cannot be applied

(All the above based on (hopefully correctly understood) analysing these sources...)
@ACuriousMind could you please sketch this?
draw a picture please :3
Since $\Gamma$ is closed as a subset of $I\times J$, we need that for every pair of sequences $x_n\to x,y_n\to y$ with $x_n,x\in I, y_n,y\in J$ and $f(x_n) = g(y_n)$ that $(x,y)\in I\times J$. If one of the intervals $\lvert i_0,i_1\rvert,\lvert j_0,j_1\rvert$ is open, say $(i_0,i_1]$ and $i_0$ is not in the boundary of $I$, then there is a sequence $x_n\to i_0$ from which we can form a sequence $(x_n,g^{-1}(f(x_n))$ that is in $\Gamma$ but whose limit point is not.
...that second $I\times J$ should've been a $\Gamma$.
I understand the first sentence.
(the definition of closedness :P)
Just to check, it's closed because it's the preimage of $0$ under $(x,y)\mapsto f(x)-g(y)$, right?
15:25
It took me a long time to realize that's why graphs are closed
@0celo7 Let me perhaps rephrase the second sentence then: If $i_0$ and $g^{-1}(f(i_0))$ both lie in the interiors of their respective intervals, then for $x_n\to i_0$ with $i_1 > x_n > i_0$, $(x_n,g^{-1}(f(i_0)))$ is a sequence in $\Gamma$ whose limit point is in $I\times J$ but not in $\Gamma$, so $\Gamma$ would not be closed.
@ACuriousMind I did not read the second sentence yet :P
I was simply reporting my progress.
@ACuriousMind Mmm, this might make sense.
what intervals though
@0celo7 By "their respective intervals", I mean $I$ respectively $J$.
wait wait what does this have to do with the boundary of $I\times J$
I really need a picture :<
@0celo7 Currently I'm just discussing how the connected components of $\Gamma$ must look. Right now I'm essentially saying the components not ending on a boundary must come from closed intervals $[i_0,i_1],[j_0,j_1]$ in $I$ resp. $J$.
15:36
Good lord I don't know what's going on
What question are you answering
Explaining what I think is Milnors argument
This is one of the steps
Which step??
More precisely, it's the first of two steps to explain why the components of $\Gamma$ must end on the boundary.
The next will be to explain why $\Gamma$ can't actually have components coming from such a closed interval.
Which is hopefully simpler as follows: This would mean that a connected component of $f(I)\cap g(J)$ is closed in $M$ - which cannot be since all connected components of that are open in $M$ and $M$ has no clopen subsets since it is connected.
@ACuriousMind I still don't understand what step you proved
What exactly did you show
@0celo7 That all connected components of $\Gamma$ are of the form $\{(x,y)\mid x\in [i_0,i_1]\subset I, y\in [j_0,j_1]\subset J, f(x) = g(y)\}$ unless $i_0,i_1,j_0,j_1$ are on the boundary of $I,J$ in which case the intervals can be open if $I,J$ are open there.
And then I gave an argument that such components can't actually exist, so all components must belong to the exceptional case where at least one of $i_0,j_0$ and $i_1,j_1$ is on the boundary.
(Then what's left is to count how many components you can actually get by this without getting two $y$ with $f(x) = g(y_1) = g(y_2)$, and that's two components.)
16:03
@ACuriousMind I'm sorry, I have to look at this tomorrow
And probably again Monday
And Tuesday morning
And then Tuesday afternoon tell my prof I don't get it
Possibly a huge chunk of info I am missing, including the details about $\Gamma$
therefore this pics is not even coherent
X(
NB do not ask me for a caption of this pics, because I am missing possibly the first half of the problem
thus it probably does not make sense
(Unless you guys, as usual, somehow can connect the dots as yoou are ver good at piecing my brain together by supplying the words I want to say)
The SW equations on 4-manifolds and the Bogolmony equations on 3-manifolds both have solutions that are called monopoles. What's the physical relationship between the two?
17:39
0
Q: Starting from an expression of E(V) and P(V), is there a way of obtaining an expression for E(P)?

DavidC. I have a question about my Physics Stack Exchange post: Starting from an expression of E(V) and P(V), is there a way of obtaining an expression for E(P)? Does anyone have an idea on how to solve this issue? Thanks

@MikeMiller Both are the equations of motion of a physical theory that has a notion of electric and magnetic charge and where the magnetic charge associated to the field $F$ is a topological invariant.
Also, the solutions "look like" the magnetic charge is concentrated at a single spot.
If $(A,\phi)$ is the input data (one a connection, the other a section), what do we mean by the electric and magnetic charge?
How can we determine that the Hilbert space of nonrelativistic QM is $L_2$
But QFT isn't
@MikeMiller The electric charge "within" a 2-cycle $C$ is $\int_C F$ and the magnetic charge within a $d-2$-cycle $D$ is $\int_D {\star} F$
Is it related to the CCR
17:43
And when you say they're the equations of motion, do you mean that if I put these equations in temporal gauge on $\Sigma \times \Bbb R$, where $\Sigma$ is of lower dimension, then the equation becomes time-evolution of a system on $\Sigma$?
Certainly this is true of SW, which is the time-evolution eqn of the Chern-Simons-Dirac functional, though I'm not sure if CSD is physically interesting.
Thanks for your patience, by the way.
So this episode of the Flash has a physicist talking about time travel
And his blackboard is nuclear physics
How gauche
@MikeMiller Actually, they are the equations of motion in two different ways ;) The Bogolmolny equations are indeed as you say something where we've forgotten the temporal part - they are actually the static part of a 't Hooft-Polyakov monopole. I think the SW equations are already the full equation of motion for the massless degrees of freedom of some SYM theory
I guess I'm not sure what it means for something to be an equation of motion, then, if it's not in temporal gauge on something of the form $\Sigma \times \Bbb R$. What does a solution represent (if it 'solves the equations of motion')? A stationary point of an appropriate functional?
@MikeMiller Yes, an equation of motion is the Euler-Lagrange equation for an appropriate action functional
ehehe, my ignorance shows.
17:50
(well...you have areas in physics where not all equations of motion come from an action, but this isn't one of them)
Anyway, thanks. I guess I have a little homework.
You never heard of the equations of motion @MikeMiller? :D
I got a B in physics 1.
Of course, I've heard of them, but my personal equation of motion dictates I usually run in the other direction when I see them.
Nice
Minimize that action, boy!
 
1 hour later…
19:02
@Slereah Well, the point is not that the Hilbert space "is $L^2$. All quantum mechanical Hilbert spaces are abstractly isometrically isomorphic to $L^2$ because they are all assumed separable
What matters is the representation of the algebra of observables, and it is the Stone-von Neumann theorem that tells you that there is only one isomorphism class of representing the CCR for finitely many degrees of freedom - of which the canonical representant is $L^2(\mathbb{R}^n,\mathrm{d}x)$ with $x$ as multiplication and $p$ as differentiation.
For infinitely many degrees of freedom, the SvN theorem fails, and there are uncountably many non-isomorphic representations of the CCR of fields
Small question: My lecturer said $H^n(T^n,T^n\setminus\text{pt})\cong H^n(I^n,\partial I^n)$ due to excision.
What do I excise?!
(first note that $\partial I^n$ is a defo. retract of $I^n\setminus\text{pt}$)
Makes no sense to me... $T^n$ is not a subspace of $I^n$...
$I^n$ the n-cube and $T^n$ the n-torus, or what are these things?
Yes
Pick a small ball around the point and excise its complement. You get that the first thing has the same relative homology as $H^n(B^n, B^n - 0)$.
Now use the relative long exact sequence to show that $(B^n, \partial B^n) \to (B^n, B^n - 0)$ induces an isomorphism in (co)homology.
Sure
Thanks.
I was thinking in terms of $T^n$ arising from $I^n$, while I should've been thinking the other way around.
19:11
Right, that isomorphism has nothing to do with the dimension of the cohomology group or the manifold used as input.
Any manifold has $H_n(M, M - p) \cong H_n(B^n, B^n-0) \cong H_n(S^n)$.
@MikeMiller Just defo retract is fine right
@MikeMiller Yes, I know that.
I just failed to remember it :)
It's - it's in the book
Yes, I know that.
@Danu Be careful. Can you say precisely the argument you have in mind? I can think of two ways it can be wrong.
@MikeMiller $B^n\setminus 0$ deformation retracts onto $S^{n-1}$
19:14
So why are the relative homologies $H_n(B^n, B^n - 0)$ and $H_n(B^n, S^{n-1})$ the same? Give me some axiomatics or something.
@MikeMiller The deformation retraction induces a chain homotopy equivalence, no?
(also, if you're referring to axioms for homology, we didn't do those)
Yes, between $C_*(B^n - 0)$ and $C_*(S^{n-1})$. Do you see why you're not answering my question?
Functoriality in the pair, something something?
Functorial dependence of relative homology on the pair, no?
I'm unsatisfied, since I docked points on a similar argument recently. But perhaps the physicists are going to grow tired of our garbage soon.
@MikeMiller ?? But really though, isn't functoriality enough?
19:19
Yes, there is indeed an induced map $H_k(B^n, S^{n-1}) \to H_k(B^n, B^n - 0)$. Why's it an isomorphism?
Use the homotopy inverse?
Now we're at the crucial problem. The homotopy inverse of what?
Of the map of pairs, right?
So you need to show that the prism operator descends to a prism operator on pairs
(which we did in class)
Ah, and the jig is up. What are the maps of pairs $(B^n, B^n - 0) \to (B^n, S^{n-1})$?
It's up... for me? :(
19:23
The point is, if $f(B^n - 0) \subset S^{n-1}$, then $f(0) \in S^{n-1}$ by continuity. You cannot possibly write down a homotopy inverse of that map; those two pairs are not homotopy equivalent.
@MikeMiller Now comes the part where you enlighten me? :D
My prof. completely glossed over this, and I never thought about it.
That was the enlightenment. Your argument does not work, because there is no good map of pairs in the opposite direction. Indeed use what I said above to prove that any map $(B^n, B^n - 0) \to (B^n, S^{n-1})$ induces zero on $H_n$.
However, if you have a map $(A,B) \to (X,Y)$ that induces an isomorphism $H_k(A) \to H_k(X)$ and $H_k(B) \to H_k(Y)$, (or on homotopy groups etc) it induces an isomorphism on homology of the pair $(A,B) \to (X,Y)$, by the relative LES and the five lemma. That's all you needed.
The relative LES for what pair?
Both of them. The LES is functorial.
You get a diagram with two infinite rows.
Ah, a ladder diagram,
Of course, I should've known when you said 5 lemma.
19:28
Uncouth.
I love the five lemma. You don't?
@MikeMiller Wait a moment, how can you first say that any map $(B^n,B^n-0)\to(B^n,S^{n-1})$ induces zero and then tell us that there are maps that induce isomorphisms on homology? oO
I really loved proving it.
@ACuriousMind Induces zero? What?
The 5 lemma thing obviously works.
@ACuriousMind It's a map in the other direction :)
@MikeMiller Ahhhh
19:30
It really upset me to realize this when I was grading that homework.
So... You also didn't know this before?
@Danu What "What?" - Mike said that "any map $(B^n,B^n-0)\to(B^n,S^{n-1})$ induces zero on homology", and this confused me.
That'd make me feel less terrible about myself.
The map $(B^n, S^{n-1}) \to (B^n, B^n - 0)$ induces an isomorphism on all homotopy groups but is not a homotopy equivalence; relative Whitehead doesn't apply to the latter, since it's not a CW pair.
@ACuriousMind I just didn't read 'till the end of that message of his. Sorry :P
19:32
@Danu I was not consciously aware of it, no. But I'm supposed to be careful when grading.
I'm sure Hatcher points this out at some point, since he always does.
@MikeMiller So what is the other way it could be wrong? ;)
(you said you could think of two ways)
Also thanks a lot for that little lesson.
The less subtle mistake is thinking that if $A$ has the same homology as $X$ and $B$ has the same homology as $Y$, then $H_k(A,B) \cong H_k(X, Y)$.
Right.
One needs a map inducing both the isomorphisms $H_k(A) \to H_k(X)$ and the same for $B, Y$ at the same time.
Really, I love the five lemma.
It was essential for me to understand the "spirit" of diagram chases.
Use surjective maps to go up/left/right/down, use injective maps to close squares :)
19:39
I don't understand algebra, is all.
I'm told if you really want to understand diagram chases you should do them in abelian categories. I decided I didn't really want to understand them.
> categories
I wish I knew...
20:20
0
Q: On the infallibility of Wikipedia edit histories

Emilio PisantyThis is not really a question about this site (though it does have some impact), but I'm not sure where exactly to raise it and I'd like to pose it to this community, which can probably / hopefully help. Recently I discovered that the Wikipedia data I used to produce an Astronomy Stack Exchange ...

20:41
How can anybody say this and not find it contradictory?
in Mathematics, 28 mins ago, by Monad
@Sᴋᴜʟʟᴘᴇᴛʀᴏʟ They are not the same, but they do not have a number in-between
Re: the difference between 0.999... and 1.
:-/
@Sᴋᴜʟʟᴘᴇᴛʀᴏʟ "In between" is a bad way to try to go about showing they are the same - you are implicitly using things like that the reals are totally ordered and that there is another real between any two distinct reals.
Shouldn't graphing the numbers on a line convince them? @ACuriousMind
@Sᴋᴜʟʟᴘᴇᴛʀᴏʟ Graphs can convince you of many things that may or may not be true :P
21:37
Why is there only one H2? I'm not familiar with quantum chemistry, but is there some fundamental property of something that makes there only be one stable configuration in molecular bonds?
*covalent
@Anthony What do you mean "one H2"? What is your notion of "being the same" here?
Isn't there only one thing really meant by H2? Like it doesn't come in different varieties does it?
Like why aren't there other stable ways to combine two hydrogen atoms?
@Anthony Again, what do you mean by "varieties"? There are, for instance, the spin isomers para- and orthohydrogen
Well then maybe I'm just wrong. Are the atomic spacings constant?
I'm...not sure "atomic distance" is well-defined for something like H2, and if it is, I have no idea about its possible variation
But I'm still not sure what you're asking - the two H atoms just have one electron each - what are they supposed to do except share it with the other atom to form a bond?
In any case, this might also be more a question for the people from Chemistry
21:49
Alright, maybe this is a better question. The two electrons in H2 have some electronic structure. Are those energy levels the same in every H2 molecule? I'm just confused because I've never seen this work through, I don't know what parameters there are, and I don't know if uniqueness of solutions for differential equations plays a role anywhere in this.
I would say that the energy levels in para- and orthohydrogen are different (but very close), similar to the (hyper) fine structure of atomic orbitals, but I'm really out of my depth here
One thing I can say, though: You've never seen anyone "work through this" because there is nothing to work through - we can't solve for any orbitals analytically except for the lone hydrogen atom. all others must be computed in approximations and numerically.
22:44
The potential energy in a capacitor is cV^2/2. More generally the potential energy stored in a voltage difference is the integral of voltage with respect to charge. Likewise, the kinetic (I guess) energy stored in an inductor is LI^2/2 and the energy stored in a moving current is the integral of current with respect to the integral of voltage with respect to time. What does the integral of voltage with respect to time mean? It's like charge is for voltage but for current.
22:56
@Anthony There are bonding and anti-bonding molecular orbitals available, but the ground state is to have both electrons in the bonding orbital (and two fit because of the spin degeneracy).
And @ACuriousMind is right bout the para- and ortho- but you need a pretty good spectrometer to discern the splitting.

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