yuggib had helped me on understand the group theory part of the things, but a lot of us here are not known to have the spectroscopy background needed for that question (so far I have asked 5 people on that question already, Kevin said he might got an answer, but he want to see what others said first)
@yuggib
Something like using operators and scrodinger equations to descibe all kinds of relaxation process in an electronic system with many electornic levels, and the system in question is a multielectorn system