No, $\psi^{\alpha}$ is a complex number, $\psi^{*\alpha}$ is another complex number, I multiplied two complex numbers $\psi^1$ and $\psi^{*1}$, did the same with $\psi^2$ and $\psi^{*2}$, then just added the result of this trivial multiplication when I wrote
$$\delta_{\alpha \beta} \psi^{\alpha} \psi^{*\beta} = \psi^{1} \psi^{*1} + \psi^2 \psi^{*2}$$