Choose any $a \in K$ and consider the evaluation homomorphism $\operatorname{ev}_a: F[x] \rightarrow F[a]$. Now apply the isomorphism theorems. Certainly, $\operatorname{Im}(\operatorname{ev}_a) = F[a]$.
Now, notice that $\ker\operatorname(ev_a)$ cannot be trivial. Otherwise, we'd have $F[x] \cong F[a]$, which is absurd since the latter is a field and the former is not. Therefore, the homomorphism has nontrivial kernel, which is precisely those polynomials with $a$ as a root.