« first day (10 days earlier)   

06:36
@Poutnik what a pity OpenAI blocks us...
@Poutnik oh, nice!
@Poutnik really?
06:57
The remote sites rarely block you. It is usually - ehm - The-man-in-the-middle.
@PetəíŕdtheWizard Every fun is real.
07:09
VPN would help but it doesn't work...
07:24
Both cases occur.

1. OpenAI restrictions: OpenAI blocks access to ChatGPT in certain countries due to legal, regulatory, or business reasons. These include countries like China, Russia, North Korea, Iran, and Syria, among others.


2. Government restrictions: Some countries block access to OpenAI services themselves, either for censorship reasons or to promote local alternatives. For example, China heavily restricts many foreign AI services, even if OpenAI does not explicitly block them.



In some cases, both factors play a role.
I can access openai.com so it's most likely the first case.
The usage of the terms lunch, supper, and dinner varies between English-speaking countries, regions, and even individual families. Here’s a general breakdown:

1. Lunch

Typically refers to the midday meal.

Common in the U.S., U.K., Canada, Australia, and other English-speaking countries.

Generally eaten between 12:00 PM and 2:00 PM.


2. Dinner

Usually refers to the main meal of the day, which is often in the evening but can also be midday in some regions.

In modern usage (especially in the U.S. and urban areas of the U.K.), dinner is commonly the evening meal, eaten between 6:00 PM an
Regional Variations

In parts of the U.K. (especially Northern England, Scotland, and some rural areas), "dinner" still refers to the midday meal, and "tea" is used for the evening meal.

In the southern U.S., "supper" is more commonly used than "dinner" for the evening meal.

In Australia and New Zealand, lunch and dinner are the common terms, but supper may refer to a light snack before bed.


Summary

Lunch → Usually midday.

Dinner → Can be either midday (older/rural traditions) or evening (modern usage).
Regional Variations

In parts of the U.K. (especially Northern England, Scotland, and some rural areas), "dinner" still refers to the midday meal, and "tea" is used for the evening meal.

In the southern U.S., "supper" is more commonly used than "dinner" for the evening meal.

In Australia and New Zealand, lunch and dinner are the common terms, but supper may refer to a light snack before bed.


Summary

Lunch → Usually midday.

Dinner → Can be either midday (older/rural traditions) or evening (modern usage).
Thanks. Now I'm hungry :-)
In India, among English-speaking people, the terms lunch, dinner, and supper generally follow modern British usage, but with some regional and cultural influences. Here’s how they are typically used:

1. Lunch

Refers to the midday meal (around 12:00 PM – 2:00 PM).

Universally understood and used in both urban and rural areas.

Often the heaviest meal of the day, especially in traditional households.


2. Dinner

Refers to the evening meal (around 7:00 PM – 10:00 PM).

Commonly used in urban areas, restaurants, and formal settings.
Cultural Influence on Meal Terminology

Many Indians, especially in rural areas or among non-English speakers, refer to meals in local languages rather than English.

Some South Indian and Bengali families may call the main evening meal "night tiffin" instead of dinner.

In Anglo-Indian communities (descendants of British-Indian families), British meal terminology (including "supper") may still be more common.


Comparison with British and American Usage

More aligned with modern British usage (lunch for midday, dinner for the evening).
Being hungry is a good thing, unless it is a permanent state.
 
4 hours later…
11:14
eh i cant read so many msgs
but ic its abt supper and dinner msg
BTW sanskrit was ezzzz
11:31
@CuckooBeats lol not very much at all
@Poutnik stuck in this problem- C7H16O4 δ = 1.93 (2H, triplet, 16Hz) δ = 3.35 (12H, singlet) δ = 4.49 (2H, triplet, 6Hz)
but I think the singlets correspond to 4 OCH3 grps
but then the molecule shoud rather be symmetric aint it? and if it is then how to differ the two triplets?
@PetəíŕdtheWizard well i am totally packed up today, tighter than a rubber band.....surely go through in my free time
@CuckooBeats what is this advanced slang that even I don't know? :P
ohhh wait a sec i think there would be no spliting due to OCH3?
@PetəíŕdtheWizard there is no slang in that message
huh you dont know anything TBH
ur the nerdiest gen alpha bro
@CuckooBeats it's some misunderstanding. Never mind.
well ofcourse it is but what i meant was i have no free time today cuz my schedule has no free gaps
hmmm very understanding of you
are you sure you know nothing in chem?
cuz its awkward you still end up in a chem chat and not in any other subjects...
@CuckooBeats Well, not exactly nothing, but limited to very basic things.
@CuckooBeats I was looking through the new rooms list and saw this chat.
ohkk less seee whats your fav subject apart from programming? maths eh?
11:39
@CuckooBeats nooo eww
lol
I love maths dude, dont you dare say ew
gotta go bye
Well I don't really have a favorite subject.
Maybe biology, but not sure.
@CuckooBeats Cya later
yeah so that means you like all the subjects equally and devote equal time to each which is actually a good thing
hmm biology then botany only i suppose
lets not flood messages till sir poutnik comes, or else he aint seeing my homework problem ;)
@CuckooBeats maybe, though I lost interest in this over years. I used to enjoy plants.
@CuckooBeats nah I'm sure he reads everything ;)
12:01
@CuckooBeats They weren't intended for you, Princess, but for Wizard, as ChatGPT blocks access from Russia.
@CuckooBeats My NMR exercises are about 40 years old...
@CuckooBeats Like the Gauss formula for numerical integration with non-equidistant point placement, based on Czebyshev orthogonal polynomials.
@PetəíŕdtheWizard If you like biology, it may be for Cuckoo the second worst thing after eating beef.
 
1 hour later…
13:25
@CuckooBeats That would leave 3 C and 4 H. Like (CH3O)2CH-CH2-CH(OCH3)2
13:44
sir is gonna teach for like 7hrs non-stop
anyways
today classsss at 11pm IST what r u guys doing in your 11pm??
13:56
@PetəíŕdtheWizard can u imagine like i realized 2 days before exam that my book was new and that some more details were added
becuz i cant XD
@Poutnik but there are two distinct triplets is it not?
u drew a symmetrical str
14:10
lol
wanders out
14:25
need some time to refresh nmr knowledge.
On the walk on crunching snow now....
 
1 hour later…
15:35
@CuckooBeats There are, now that are those with high shift?
2. Chemical Shift (δ, ppm)

Determines the electronic environment of the proton.

Typical ranges (approximate values):

0–3 ppm: Alkyl (CH₃, CH₂, CH)

2–3 ppm: Protons near electronegative groups (e.g., -C≡C-H, -CO-CH₃)

3–5 ppm: Protons near oxygen or halogens (-O-CH₃, -Cl-CH₃)

5–7 ppm: Alkene protons (-C=CH)

6–9 ppm: Aromatic protons (benzene ring)

9–10 ppm: Aldehyde (-CHO)

10–12 ppm: Carboxylic acid (-COOH)
meh i prefer it thru the logical way
aint no way i can remember those valuessss
grabs pete again, throws him in the snow, so that he can never wander in ever again
ahem ok that was violent
@CuckooBeats now that was unnecessary
eh actually poutnik has been using advantage over my snow-obsession
cuz aint no snow in india here, atleast not in the eastern coast
15:44
It's been snowing recently.
It stopped at 40 cm.
@CuckooBeats Normal people sleep at 11 PM, or are having some late evening fun, whatever that means.
meh could be a metal hydride.
@CuckooBeats Any interest in MMA?
@CuckooBeats Shift raising with pulling electron density.
@CuckooBeats Taking advantage over obsession is safe. I would never dare taking advantage over the obsession carrier.
meh could be methyl Hindi.
I'm not particularly obsessed with snow, though.
Maybe, if only I had a bicycle that had actual tires that can actually ride in snow...
What about the fear of snow?
15:53
Nah, I don't fear snow.
I know meh is not abbr nor acr, but why not to pretend it is?
Fear of snow to be cleaned up for people or car to pass.
@Poutnik nailed it :D
@Poutnik oh, well, we don't have such deep snow.
I like to play with words.

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