Chemistry told me Anamolous expansion is because water gets into Hydrogen bonding ands gets arrange in a very spacious lattice (Each water molecule is tetrahedrally attached to other)
Not sure if Im right in this part, most probably wrong, but In Clausius Clapeyron Relation delta S/ delta V must be +ve though delta V is negative since final entropy is lesser. Ice's possible microstates for the given state variables is much lesser than Water because of the spacius lattice arrangement by H bonds