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2:01 AM
okay, done
with both commands
wait, what...
i checked the version
 
and?
 
and it gave 1.7.9.5
exactly what it gave before
 
Apparently there is a theorem why QFT can't use operator valued functions
Due to Wightman
But that paper doesn't show the proof
It seems to be that if you try that every field operator just sends back the vacuum
 
@heather :\
 
@ACuriousMind halp
 
2:06 AM
is there a specific update command i can use on git?
or do i need to say install git 2.whatever?
 
@heather Hm
What's the output of $lsb_release -a
 
a bunch of stuff, among it Ubuntu 12.04.5 LTS
 
Ah, that's why
that's old
 
hahahaha
oops
lol
Why didn't I think of that?
 
sudo add-apt-repository ppa:git-core/ppa
sudo apt-get update
sudo apt-get install git
 
user228700
2:09 AM
Does anybody know any physical chemistry? I have a quick question about the dew point and exactly what it means :-|
 
@heather That
You need a special repo to get the latest git releases since you have old Ubuntu repos
 
okay
 
@Slereah What do you need
 
@BernardMeurer I guess that's one way to do it.
 
umm... add-apt-repository: command not found
 
2:10 AM
Would upgrading her distribution be a bad idea?
 
@DanielSank Idk, I don't want to do anything risky
 
and i made sure to use sudo
 
@BernardMeurer okey dokey
It's just easy to forget what ppa's you've added.
No big deal.
 
do i need to go into the main directory instead of the /calculus-notes one, or...?
 
@heather Did that work?
 
2:16 AM
going into the main directory @BernardMeurer? no, command not found again =/
 
@heather You sure you're writing it correctly?
This really should work
sudo apt-get install python-software-properties
You need this package
then you can do add-apt-repository
 
okay, I'm installing the package
okay, now the add-apt-repository worked
 
@BernardMeurer Never feel bad for interrupting someone trying to teach people wrong things. These people are a plight, they are only able to spread misinformation precisely because no one ever stands up and calls them out on it.
 
okay, update done
installing git...
 
@ACuriousMind Yes, but be nice about it.
Embarrassing someone in public is almost always a very bad idea.
 
2:21 AM
git installed, did git --version
and it gave 2.10.2
 
woopie!
 
::fist-pump::
 
lol
 
:)
@ACuriousMind That's what I thought
 
@ACuriousMind Do you happen to know where I can find Wightman's proof of functions not working for QFT
 
2:22 AM
@ACuriousMind I'll talk about this more tomorrow
I gotta go folks
 
Also this paper doesn't include the CCR as an axiom, is it unnecessary
 
@DanielSank If that someone holds some sort of power over you, yes. Otherwise, it is sometimes necessary. Sure, don't be mean for the sake of being mean or appearing superior, but also don't concede points simply because it would embarrass the other party showing they're wrong/baseless.
 
@BernardMeurer, have a good night! =) thanks for your help!
 
@Slereah Not in those words. What exactly do you want to show?
 
@ACuriousMind There are ways to add new information without making the other person's wrongness the focus.
This is a very important skill.
"Oh, I've studied that a bit. I have some information to add."
You can directly contradict what the first person said without ever saying "what you said is wrong".
From a scientific point of view, note that the fact that the first person was wrong is irrelevant.
Pointing it out serves no purpose.
 
2:25 AM
@DanielSank, okay, I cd'd into the /calculus-notes directory
 
@heather k...?
 
@DanielSank, oh, I just was going to see if push didn't work now on the second branch
 
@DanielSank But why should you? If they're wrong, they're wrong. It's not relevant that the person was wrong, but it's important that you are not "adding information" but correcting what was said. "That's wrong" takes a lot of confidence to say, but if you are confident it is true, you should not dance around that fact.
 
@ACuriousMind Apparently the theorem is something like, if you use operator valued functions as a basis for Wightman's axioms, you get something along the like of $\hat \Phi (x) |\psi\rangle = c|\Omega \rangle$
For some constant $c$
 
whoa, now I've got a new problem
what is it with me and these weird problems?
 
2:28 AM
"From a scientific point of view", there's no shame in being wrong. Scientists are wrong all the time. The important thing is that we own up to our mistakes.
 
::sighs::
it says that it can't find any of my tex files in any of the branches when I try to add them
dunno what's going on there
i'm going to take a break from this for a little bit and come back to it
i think I'm about to go find Tux and smack him =P
 
@Slereah You mean you replace the statement "fields are operator-valued distributions" by "fields are operator-valued functions" and then that's the result?
 
It seems to be related to the Poincaré invariance of the vacuum
Apparently that is the claim, yes
 
Well, how is the CCR supposed to look like if they're not distributions?
 
@ACuriousMind Unfortunately, human feelings etc. matter quite a lot in the pursuit of education and science at large.
 
2:30 AM
The axioms do not include the CCR, strangely enough
At least not in this paper
 
You can't write $[\phi(x),\pi(y)] = \delta(x -y)$ if $\phi,\pi$ are not distributions.
 
@ACuriousMind I can't tell why you're arguing this point.
Yes, we should all detach our emotions from science. You know damn well this is not how the world actually works.
 
I checked Glimm and Jaffe and they are also not on the list of Wightman axioms
 
@Slereah Sure they aren't because the Wightman axioms don't really know about a Lagrangian or $\pi$.
 
@heather I might know why that happened and how to fix it. Not sure though. Can help later.
 
2:33 AM
But they have both field operators and momentum operators
Can you derive the CCR from Wightman or do you have to include them in specific theories?
Can you have a non-CCR/CAR theory of QFT
Also non-CAnyonR theory I guess, for 2D
 
@Slereah I don't see where the Wightman axioms include a momentum operator.
 
The unitary representation of the Poincaré group
 
@Slereah That's not the conjugate momentum!
 
What is it then!
 
It's just the total four-momentum
The conjugate momentum and its CCR with the quantum field depend on the Lagrangian, which the WA make no mention of.
 
2:36 AM
But then is it mandatory or not for a quantum theory?
 
And there are QFTs without Lagrangian descriptions, and therefore without a conjugate momentum. I think I remember some variants of Seiberg-Witten theory only have "local Lagrangians", but I don't recall any details
 
Hm
 
@DanielSank I'm fully aware that it might hurt someone's feeling if I tell them they're wrong. That is, however, preferable to giving the impression that their notions and arguments have merit to them when they don't.
 
@ACuriousMind Yes, the preference you indicated is correct.
 
In any case, I've not heard about that theorem of Wightman you're talking about, @Slereah, sorry
 
2:38 AM
That paper doesn't mention a bibliographical ref for it
Quite rude
 
There is a sort of "correctness > people" idea in software and physics, and frankly it leads to a lot of would-be interested people leaving before they have a chance to learn what it's all about.
 
The bibliography only mentions one book by Wightman
Guess I'll check that one
"PCT, Spin and statistics, and all that"
The full theorem, btw :
 
Yes, correctness is prime, but people let this justify unnecessarily confrontational tone so often that I think it's worth remembering that there are different ways of correcting misinformation.
 
"Let $\Phi$ be a field in a Wightman QFT which can be realized as a map $\Phi : M \to \mathcal O$ and where $\Phi^*$ belongs to the fields. Moreover, assume that $\Omega$ is the only translation-invariant vector (up to scalars). Then $\Phi(x) = c \Omega$ is the constant operator for a suitable constant $c \in \Bbb C$"
I wonder if that spells bad news for my QFT with hyperreal idea
If the CCR are not why it doesn't work it doesn't bode well
 
@Kaumudi John R hs gone to bed, but he might know. I ought to know but fear that I don't
 
2:45 AM
@DanielSank Well, "correctness > people" is an integral part of the scientific method. I think what you're complaining about is that many people in our fields are rather bad at bringing across that this doesn't mean people are devoid of value, and that it also doesn't mean it's a personal failure to be wrong. That is, however, totally different from not saying the other person was wrong, in my view.
 
Are you sure he is not devoid of value, though
 
user228700
@dmckee I'll wait for him to wake, thanks :-)
 
Also who are we talking about
I have gotten стреатер р.ф., шигхтман а.с. пцт, спин анд статистицс анд алл тхат
Good old шигхтман
And his шигхтман axioms
"The idea of this book arose in a conversation with H.A. Bether, who remarked that a little book about modern field theory which contained only memorable results would be a good thing."
None of those boring results
This is a book 100% about great things
 
@Slereah Is there a $\Omega$ missing after your $\Phi(x)$ there? Then it would seem the intent is to show that in this case, $\Phi(x)\Omega$ is translation invariant for all $x$ and so has to be a multiple of $\Omega$.
 
There is not
The notation is a bit confusing but I think it's meant to say "It only produces the vacuum"
 
2:51 AM
$\Phi(x) = c\Omega$ doesn't make any sense, though
 
Yeah
 
The l.h.s. is an operator, the r.h.s. a state
 
Partly why I want to see what Wightman says
 
I'm afraid I really have never heard of such a theorem, my best motivation for why fields must be distributions is that we want their canonical commutator to be a distribution.
 
This seems like a pretty good book btw
Basically it's a QFT book with none of the thrills
Why do so many physics book like to sprinkle lewis carroll quotes
 
3:02 AM
@ACuriousMind I think it is wholly unnecessary to say that a person is wrong.
It is sufficient and more productive to focus entirely on the statements that are wrong.
That may sound trivial, but my goodness to people screw this up all the time.
 
Apparently $\hat \varphi(x) = \hat 1$ satisfies all axioms
A fine QFT
 
Sure, don't get up in their face and say "You're wrong!" but say "That's wrong.". And yes, that does sound trivial to me :P
 
@ACuriousMind It's not trivial at all.
 
@Slereah I can'T find the theorem your paper seems to be referring to in Streater/Wightman, though
They just start off with distributions not giving much reason for it
 
Yeah I can't either
It is bothersome
I'd rather not wade through all the Wightman papers
 
3:05 AM
@ACuriousMind There's a world of difference between "Einstein was wrong about entanglement" and "Turns out that entanglement is real".
 
@DanielSank I see the difference. I'm not sure what we're arguing about at this point. I agree you shouldn't make it about the person. But you should point out wrong statement when you hear them, and there's no point in mincing words about that - if something is wrong, it is wrong. Maybe it's a language issue. In German, the phrases "You're wrong" (Du hast unrecht) and "That's wrong" (Das stimmt nicht/Das ist falsch) are not easily interchangable, so I don't really confuse them.
 
They are confused in English all the time.
Not sure why
gtg
 
Well, because you use "wrong" in both cases!
For me, a thing being "wrong" and a person being "wrong" are two entirely different concepts with their own words attached.
 
vzn
@DanielSank agreed! just wanted to say this reminds me of some psychology theory wrt distinction of "criticism vs complaining". am (long) attempting to discern/ delineate this boundary better myself gottman.com/blog/the-four-horsemen-criticism
 
The horror
 
3:15 AM
@vzn I'm afraid I don't see how a blog about resolving issues in a personal relationship is directly relevant to scientific debate. There's a large difference between a clash between two entirely personal viewpoints and disagreeing about something which can be settled by facts.
 
vzn
@ACuriousMind lol figured someone might question it on exactly those grounds and its certainly a valid point. but on other hand isnt all communication inherently about relationships? anyway have found the distinction of "criticism vs complaining" to be personally helpful, think its close to the distinction DS is making, & am aware gottman is redefining the terms somewhat from a specialist psychology pov. (many psychology terms are like that etc)
 
@vzn The point about the complaining with statements focusing on "I" and not "you" is that complaints about behaviour in a relationship are intrinsically subjective - what behaviour one person expects is not what another expects, and there's no one "correct" way of behaviour. In a scientific debate, there is an ideal truth to be discerned, and "I" statements are simply invalid because our personal feelings about facts are immaterial to their truth.
I'm not questioning the validity of the approach to discussing issues in personal relationships, but I really don't see that it is in any way transferable to discussions about objective facts.
 
vzn
@ACuriousMind think the distinction of criticism vs complaining has some relevance in scientific contexts in eg avoiding ad hominem style expression(s) something you raised yourself here somewhat recently in another context... seems to me gottman is redefining criticism as something that comments on a persons character aka nearly ad hominem. agreed facts≠feelings as is pointed out/ emphasized in some other psychological literature eg "CBT"...
 
I read the article entirely differently: A "criticism" is something that talks about a feature of the other person (not an ad hominem, it truly names a disliked feature the speaker perceives about the other person which is the problem itself) while a "complaint" is something that focuses on the speaker's personal feelings and opinions induced by the adressed person's actions.
 
vzn
> ad hominem 1. (of an argument or reaction) directed against a person rather than the position they are maintaining. "vicious ad hominem attacks"
 
3:25 AM
@vzn There is no "position" in the relationship debate posed in the link - the entire discussion is about a specific behaviour of the other person. It's not an ad hominem to fault the other person for that behaviour; it's just unhelpful.
The entire point of an "ad hominem" is that I attack my opponent's character instead of their logical argument. In a debate founded on emotions rather than logic, the concept of an ad hominem doesn't make any sense.
 
vzn
@ACuriousMind actually my opinion is that gottmans theory is limited somewhat for reasons that you man be getting at :| ... but anyway believe it or not he formulated a lot of his theory based on extensive observational psychology ie scientific research! however it can be subtle at times...
 
I'm not questioning Gottman! I don't know any of their work. But the article as written just doesn't apply to scientific debate because it is written explicitly about disagreements in a personal relationship.
 
vzn
lol. think if you read his example criticisms carefully, theyre quite similar to ad hominem statements, if not exactly that.
 
If my issue is that my partner didn't call me and I think that it's because they didn't think of me, then saying "I think you did this because you're selfish" is an attack on their character, sure, but it's not an ad hominem because my entire problem is that I feel they are selfish. There are no "ad hominem"s if the discussion is about my partner's characteristics to begin with. An ad hominem would be if I said "You're selfish, so you can't be right about which philosophy is best for all"
An ad hominem requires that there is a part of the discussion which has nothing to do with a person's character, and yet I insist on dragging their character into it to discredit them.
Not all insults are ad hominem, and not every ad hominem is an insult.
 
vzn
(btw did you take any philosophy classes?) there may be a distinction here or maybe not. having some trouble following the distinction youre making. you seem to consider debates over topics to have special status in communication. but wrt ad hominem defn quoted earlier, virtually all communication involves "positions", maybe even unspoken ones... eg in your example "not calling" could be considered a "position" (albeit unspoken)
 
3:42 AM
@vzn Well, not at university, but philosophy was one of my favourite classes in school. My point is that an "ad hominem" is a particular form of invalid argumentation in a debate based on logical reasoning by its definition. Of course emotional debates about what the participants feel in a relationship have positions, but there are no fallacies (of which ad hominem is one) in such debates because there is no "correct" way of reasoning to begin with.
It's all about subjective feelings, not about objective truth that can be arrived at with logically correct reasoning.
You can't apply the notion of "fallacy" to a debate which does not in principle have a correct outcome.
(That's a large problem in political discussions, by the way. Usually, the participants start from different, unstated premises, which makes their arguments essentially incommensurable)
 
vzn
"ad hominem" is just an adjective based on its defn. agreed it is often/ typically applied to arguments but dont think thats the only valid context. actually gottman was indeed describing arguments in his own distinctions... actually do think there are fallacies wrt emotions, but its complicated...
 
4:13 AM
Hi, everybody.
 
user116211
4:59 AM
@DanielSank o/
 
5:16 AM
@MAFIA36790 \o
 
 
1 hour later…
user228700
6:29 AM
@JohnRennie: Morning :-) Are u busy?
 
Morning Kaumudi.
I saw your question yesterday but didn't get round to answering.
Is that what you want to discuss?
 
user228700
Yes, that and a few more questions that have come to mind this morning. Are u busy..?
 
No, now is a good time.
19 hours ago, by Kaumudi
OK, Yahoo Answers aren't at all reliable but I found this:
 
user228700
Alright then, let me find the questions...
 
user228700
> "For most liquids, is the dew point temperature higher than that of its boiling point?"
 
6:32 AM
Pure liquids or mixtures?
 
user228700
Ooh, I didn't think that would make that much of a difference here, but I speak of mixtures...
 
Let me just Google exactly what the definition of a dew point is ...
OK, I think we may be getting a bit mixed up with terminology
Dew point is the highest temperature at which airborne water vapor will condense to form liquid dew. A higher dew point means there will be more moisture in the air. Dew point is sometimes called "frost point" when the temperature is below freezing. The measurement of dew point is related to humidity. == Humidity == Given that all the other factors influencing humidity remain constant, at ground level the relative humidity rises as the temperature falls. This is because more water vapor condenses as the temperature falls further beneath the dew point. Dew point temperature is never greater than...
 
user228700
Yes, that ^ is the definition that I have learned.
 
This isn't anything to do with the phase diagrams we've been discussing.
Suppose you have air at 50% relative humidity, which means the partial pressure of water vapour has some value $P$.
 
user228700
Okay...
 
6:37 AM
If the RH is < 50% that must mean P is less than the vapour pressure of water (at whatever the ambient temperature is)
If we now start reducing the temperature the vapour pressure of liquid water falls, simply because vapour pressure falls with temperature.
At some temperature the vapour pressure of the liquid water falls below P. At that temperature the particla pressure of water vapour in the air is now greater than the vapour pressure of liquid water, so the vapour in the air starts condensing to water.
That is the Dew point - or I suppose it should really be the dew temperature
 
user228700
I'm afraid I don't quite understand. Please give me a moment...
 
user228700
> "Suppose you have air at 50% relative humidity, which means the partial pressure of water vapour has some value $P$."
 
user228700
^ This doesn't make sense with:
 
user228700
> "If the RH is < 50% that must mean P is less than the vapour pressure of water (at whatever the ambient temperature is)"
 
user228700
One second...
 
user228700
6:45 AM
Alright, forget the first statement. What dyou mean by the 2nd one?
 
Suppose the temperature in your room is 30C. A quick Google tells me the vapour pressure of water at 30C is 0.0419 atmospheres.
 
user228700
OK...
 
So if the air in your room is in equilibrium with water the partial pressure of water vapour in the air (at 30C) will be 0.0419 atm. Yes?
 
Two identical rooms in a house are connected by an open doorway. Temperatures of either are different. Which room has more air?
 
user228700
Yes...
 
6:47 AM
And that' what we mean by 100% relative humidity i.e. the partial pressure of the water vapour is as high as it can be.
 
Is the amount of air same? Or higher/lower has more temperature.
 
user228700
Yes...
 
So 50% RH means the partial pressure of the water vapour is (John struggles to divide by two) 0.02095 atm.
 
user228700
:-P Right...
 
And that's all I meant by "If the RH is < 50% that must mean P is less than the vapour pressure of water (at whatever the ambient temperature is)"
P is the partial pressure of the water vapour, 0.02095 atm, and it's less than the vapour pressure of liquid water 0.0419 atm.
 
user228700
6:50 AM
Alright, OK, I understand :-)
 
user228700
@SwapnilDas Hi :-) The amount of air will be different. Use the ideal gas equation to figure it out. (Although, if it's an "open doorway" and all, I don't understand how the temperatures are different)
 
Anonymous
Identical rooms so V will equal.
connected by an open doorway, P will be equal, if not there will be a wind , and the after some time P will equal for both room.

Now use PV=nRT for each room.
 
Anyhow, looking at the table of water vapour pressure the vapour pressure of liquid water falls to around 0.02095 somewhere between 15C to 20C.
 
user228700
@JohnRennie: I've re-read your explanation from a few minutes ago and I understand it. This is not the dew point we've been discussing in phase diagrams?
 
Anonymous
@Kaumudi Suppose you have an air conditioner in one room and keep the door open :-P
 
6:54 AM
@Kaumudi No, because the dew point only happens because the air is not saturated with vapour i.e. it is not in equilibrium with the liquid.
Assuming we're using the common definition of dew point
 
Just made an SQL database for my music collection.
Can search by album year, track name, genre, etc. etc.
Now need to figure out how to populate it.
Probably will an a field for URL's for each track. Can point to Youtube or Google Drive or whatever.
 
@DanielSank If you're talking about mp3s I have some code somewhere that reads the mp3 tags. You could adapt that to populate the database.
 
@JohnRennie Cool.
I have a Windows program that can read data from an online CD database, but I don't know how to get at that data from python.
If you have something that can read the metadata from mp3/flac/whatever files, that could help.
 
user228700
@JohnRennie Ah, yes.
 
Unfortunately, I think the metadata stored by most CD ripping software is dumbly structured... but I can fix that I guess :)
 
6:59 AM
@DanielSank Actually that code uses an ActiveX component so probably not ideal for you. There must be a Python module to read mp3 tags.
 
@JohnRennie There is indeed, you're right!
 
user228700
(Sorry, was attending a phone call from my grandpa)
 
@Kaumudi by definition the dew point is a lower temperature than the boiling point because it assumes we start with the partial pressure of the vapour lower than the vapour pressure of the liquid.
 
user228700
Exactly ^ ! This was my confusion at first. Alright, what then is the definition of the dew point with regard to phase diagrams?
 
@JohnRennie If you're interested, @BernardMeurer and I are starting to work on a chat server in Rust, for the sake of learning Rust.
No code yet. I've been doing some basic tutorials etc.
I'm kinda interested in learning to add crypto too.
 
7:02 AM
@Kaumudi It is the highest temperature that the vapour can be in equilibrium with liquid. So for a pure liquid it is just the boiling point.
 
user228700
Isn't that the bubble point? O.o
 
If you start at a high temp and follow a line of reducing temp downwards then the dew point is where liquid first condenses i.e. where you hit the upper line on the phase diagram.
@Kaumudi The bubble point is starting at low temp with the liquid and increasing the temp until vapour first appears
 
user228700
This is what my textbook says:
 
So it's starting at the bottom of the phase diagram and moving upwards until you hit the lower line.
 
user228700
I was about to ask you s'thing related to this but suddenly, I am facing a crisis with technology. May I ask?
 
7:08 AM
Yes, I'm a geek as well as a nerd :-)
4
 
user228700
It's my grandpa's phone. He wants me to sell it online to whoever is willing to buy it. But it looks like the battery is kaput. I've charged it for 3 hours now and it still isn't switching on!
 
what model of phone it it?
 
user228700
To tell u the truth, the phone itself is kind of useless so I highly doubt if anybody will buy it so I'm wary about spending money to buy a new battery and all.
 
Morning
 
user228700
@JohnRennie My grandpa doesn't remember and the wretched thing isn't switching on, so I don't even know which model it is. All Ik is that the company is Micromax. Let me check...
 
7:13 AM
@Kaumudi I agree. Leave the phone charging overnight and see what happens. Try to turn it on with the charger still connected. If it still won't turn on then the phone is probably bust.
 
user228700
@JohnRennie We charged it the whole night, last night.
 
If it won't turn on with the charger connected then either the charger or the phone isn't working.
 
user228700
I didn't try to switch it on with the charger still connected to it. What difference does that make..?
 
If the battery is dead the phone should still work using power direct from the charger.
 
user228700
Also, the charger works perfectly fine.
 
user228700
7:17 AM
OK, give me one second...
 
user228700
It says "Charging" now :-/
 
user228700
So the battery's dead? (Because we charged it the whole night, last night!)
 
Anonymous
@Kaumudi Is it a smartphone ?
 
user228700
Yep.
 
Anonymous
With touchscreen ?
 
7:21 AM
It certainly sounds as if the battery is dead. The phone may still have some resale value though, even with a dead battery.
 
user228700
This is it:
 
user228700
The rear camera is about 2 mp. I doubt if anybody will buy it. My grandpa wants me to advertise it for Rs. 2000 but I dunno if anybody will be interested. I'll show u a picture of its beautiful (sarcasm) frame, hang on...
 
Anonymous
@Kaumudi You can sell it on EBay. But you need to mention it has no battery. There are some people who recycle old phones. You will get a good amount in case it has a touchscreen and/or is a smartphone. But don't expect more than INR 1000. But before that try talking with some local shops which repair phones (because the phone might be having some important data and memories attached :) ).
 
user228700
^ Firstly, my grandpa reset the phone so no worries about "important data/memories" :-P
 
user228700
7:26 AM
Secondly, EBay? I was thinking Olx...
 
Anonymous
@Kaumudi I don't think on OLX they will take a phone which isn't even switching on...
 
Anonymous
EBay buys almost everything...though you can try on OLX
 
user228700
Damn :-/ Alright, I will try EBay.
 
user228700
Thanks, guys :-) My grandpa will be happy to know that there is some hope, after all.
 
user228700
@JohnRennie: For how much longer will u be around?
 
Anonymous
7:28 AM
@Kaumudi Good luck with the phone :)
 
@Kaumudi Several hours ...
 
user228700
@S007 Thanks :-)
 
user228700
Awesome! I'll be back in a hour at most. First, I need to have lunch and then if there's time before the hour is up, I need to deal with this phone.
 
Mew
7:50 AM
Sup peeps
@JohnRennie do you have an interest in psychology?
 
@Mew it's not a subject I've ever studied
 
Mew
neither but it is a subject that interests me
But it suprises me how underdeveloped the field seems to be
@JohnRennie have you heard of Maslow's hierarchy of needs
 
@Mew No
 
Mew
It is a pyramid that is meant to classify fundamental human needs
It is from 1943 and I still today can't find a more up to date theory
 
user228700
8:27 AM
@Mew I have :-) Also, hello!
 
user228700
@Mew Have u read The Fault in Our Stars?
 
user228700
 
user228700
 
user228700
 
user228700
 
user228700
8:33 AM
@JohnRennie: I'm back!
 
Nice lunch?
 
user228700
Yes, it was awesome! :-) Fried rice, raita and okra fries. Mm.
 
960 on the physics GRE! Woohoo!
 
user228700
^ Congratulations :-)
 
user228700
@JohnRennie: More questions?
 
8:39 AM
Yes?
 
user228700
Gimme a moment to find them again...
 
user228700
Alright, this is what my textbook has to say about the dew curve and the bubble curve:
 
user228700
> "The dew-point curve gives the boiling temperature at the given pressure as a function of the mole fraction in the vapour phase. The bubble-point curve gives the boiling temperature at the given pressure as a function of the mole fraction in the liquid phase"
 
user228700
Does that make sense? ^
 
That's OK, though don't confuse that use of the term dew point with the way it's used to describe, for example, formation of dew when the weather is cold.
 
user228700
8:46 AM
Uhhhh.
 
The phrase dew point has (at least) two different meanings
And they are only vaguely connected.
 
user228700
They're vaguely connected, that's the problem! Alright, never mind this. I think I'll be able to figure it out in awhile.
 
user228700
May I ask u questions about distillation of azeotropes?
 
@Kaumudi Yes, of course
 
user228700
:-) Alright, this is the phase diagram for a minimum boiling azeotrope:
 
user228700
8:51 AM
 
user228700
Whilst distilling mixtures in which the concentration by mass of ethanol is greater than 95.6%, eventually, we are able to obtain pure ethanol in the vapour form, which we can then condense, correct?
 
Mew
Thanks @Kaumudi intersting read
 
@Kaumudi No. Exactly the opposite in fact :-)
 
Mew
I also think the Maslow pyramid is deficient
 
user228700
8:53 AM
@JohnRennie o.O
 
Mew
but I'm suprised that there is no more recent more comprehensive theory
 
user228700
@Mew: Yes. It's a wonderful book, BTW.
 
Mew
what is it about?
 
user228700
Google TFiOS :-)
 
Mew
oh
I may have seen a bit of that on tv once
it looks sad
 
8:55 AM
@Kaumudi Suppose you zoom in on the right hand side of the phase diagram, and draw a horizontal line at some temperature $T >95.6C$ to find out the liquid and vapour concentrations that are in equilibrium.
You'll find that the vapour has a lower mole fraction of ethanol than the liquid does.
 
user228700
@Mew Very much so, I'm afraid.
 
user228700
@JohnRennie Yes...
 

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