@janos there are a couple of reasons:
1) With my enjoying reviewing SQL I frequently run into PHP-MySQL questions, where I can only address the SQL, normally a small part of the script. So if I get good at PHP I can review everything.
2) I feel it's such a popular language (#5 top number of questions on CR, for example) it would be useful and I can even use it for my own projects.
3) There's 81 PHP zombies needing an answer ;)