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@JonathanBeardsley to have an "underlying \infty-category", all you need is a relative category (via the barwick--kan model structure), not even a model category -- let alone a simplicial model category. i think it's irrelevant to your question that you happen to be examining a relative category whose objects are simplicially enriched categories
or rather, "yes" -- the underlying \infty-category of the bergner model category structure on simplicially enriched categories is indeed Cat_\infty
@HarryGindi are you asserting that sCat_Bergner is compatibly enriched over sSet_Joyal? i'm not sure i believe that