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11:00
OK, shout if you want me to clarify what I mean.
user228700
U'll probably hear me shout but ::still processing::
user228700
@JohnRennie: ::shouts:: I think it'll be quicker if u explained it. I'm not sure I'm thinking correctly about the situation...
user228700
@Mew DO NOT DISTRACT!! :-P
A liquid boils, i.e. turns to vapour, if the pressure is lower than its vapour pressure.
user228700
11:04
One moment.
Mew
Mew
:P
@Kaumudi ...
user228700
Okay, so when u say
user228700
> "boils, i.e. turns into vapour"
user228700
I have a problem with that :-P
user228700
11:06
A liquid turns into vapour even before it starts boiling...
Mew
Mew
me 2
^ what she said
Anonymous
@Kaumudi Do you know that boiling point is the temp at which liquid's vapour pressure =atm pressure ?
So there's a user called "Time Traveler"
Anonymous
The boiling point of a liquid is the temperature at which its vapor pressure is equal to the pressure of the gas above it.The normal boiling point of a liquid is the temperature at which its vapor pressure is equal to one atmosphere (760 torr).
He's been asking a lot of CTC questions lately
11:07
@Kaumudi if the pressure is kept lower than the vapour pressure then all the liquid will turn to vapour. Yes?
You'd think he'd have looked up CTCs before going time traveling
Mew
Mew
@Slereah dpo you have some links, sounds interesting
user228700
@S007 'Course I do.
Mew
Mew
Give her more credit S007
Anonymous
@Kaumudi So where are you facing a problem in John's statement ?
user228700
11:08
@JohnRennie It's a little weird, thinking about changing the pressure and not the temperature but yeah, I agree.
Mew
Mew
thanks slareash
how gracious of him to visit stackexchange of all places
@Kaumudi yes, it is a bit weird thinking about changing the pressure but keeping the temp constant, and in fact that's why this all seems a bit confusing.
Anyhow, does it make sense that if $P < P_b$ then all the liquid (both A and B) turns to vapour?
user228700
@S007 Well, he said turns into vapour = boiling. That was the problem.
Anonymous
@Kaumudi Yes, that is called boiling only !
Anonymous
11:11
Boiling may be induced by pressure change too
user228700
No. That is called evaporation. If it happens so that the saturation vapor pressure is equal to the atmospheric pressure at that temperature, then only boiling occurs.
Mew
Mew
indeed
take 70 degree water to everest
and it will boil
I think this is all getting a bit distracting ...
user228700
:-/
@Kaumudi suppose I put some pure B in an evacuated sealed vessel. Then B will evaporate until the pressure inside rises to $P_b$. At that point the vapour and liquid are in equilibrium. Yes?
user228700
11:14
Yep.
user228700
$P_b$ being its saturated vapour pressure?
OK, now I increase the volume of the vessel, so the pressure drops. When this happens more liquid evaporates and the pressure rises back to $P_b$. Yes?
Yes, $P_b$ is the saturated vapour pressure at our (constant) working temperature.
user228700
@JohnRennie Brain not able to digest this completely.
Anonymous
I can't agree with that. Evaporation can occur at all temperatures.
On average, a fraction of the molecules in a glass of water have enough heat energy to escape from the liquid. The reverse also happens — water molecules from the air enter the water in the glass — but as long as the relative humidity of the air in contact is less than 100% (i.e., saturation), the net transfer of water molecules will be to the air. The water in the glass will be cooled by the evaporation until an equilibrium is reached where the air supplies the amount of heat removed by the evaporating water. In an enclose
@Kaumudi this is a key point, you need to be sure about this.
Anonymous
11:17
But what John was talking about was lowering of the BP itself by reducing pressure
Mew
Mew
@S007, you're distracting the main conversation
user228700
@S007: I'll get back to you.
user228700
@JohnRennie Yeah, Ik :-( ::Thinking::
Anonymous
Evaporation is a different thing @Kaumudi Okay, but I wanted to clear that misconception...we will get back to it later
Mew
Mew
@Kaumu, if you have a liquid in a jar, the liquid will evaporate until the partial vapour pressure in the jar is Pb
if you make the jar bigger somehow
the pressure in the jar is now less than Pb
so what happens?
user228700
11:19
@S007 I'm pretty sure this is a miscommunication and that both of us are clear regarding this concept. Still, I will get back to you to clear the miscommunication later.
Mew
Mew
more liquid evaporates
until the pressure in the jar reaches Pb again
if you expand the jar even more
the pressure drops again since PV = nRT
T and n are constant
so PV = constn
so if V increases, P drops
so if volume of the jar increases, pressure drops, allowing more liquid to evaporate
user228700
@Mew This. My stupid brain was unable to use this point. Atghf.
user228700
Okay, I understand.
Mew
Mew
yay
Anonymous
@Kaumudi I don't think it is a miscommunication. Till few months ago I had the same misconception about evaporation and boiling. Anyway I'm stopping here till the conversation ends.
user228700
11:20
Thanks @Mew. @JohnRennie: Re-reading your messages.
Mew
Mew
don't be too hard on yourself Kaumu
ur pretty smart
user228700
(Still reading)
@S007 unrelated question, thus I decided to ask you in a separate room
user228700
@JohnRennie: Okay. I agree with everything u said :-P
Anonymous
@Secret could you give the link to the room ?
@Kaumudi OK. So if I keep increasing the volume of my sealed vessel more and more of the liquid evaporates to keep the pressure at $P_b$. Yes?
user228700
Yes.
And if I keep increasing the volume until the last of the liquid has boiled then at that point the pressure starts to fall below $P_b$
So the conclusion is that if the pressure falls below $P_b$ there will be no liquid left. The whole system will just be vapour.
Mew
Mew
agreed
becuase there is no more liquid to evaporate and make up the pressure back to Pb
@Kaumudi Yes?
user228700
11:31
Okay. Have to back up and ask a really dumb question. Boiling→saturated vapour pressure of liquid=pressure of surroundings, yeah?
@Qmechanic I'm not sure just adding a google search for a term really makes a post much clearer
user228700
So in this case...
I would avoid the word boiling
All we're talking about is the vapour-liquid equilibrium
Whether you describe the liquid-vapour transition as boiling or evaporation doesn't matter.
user228700
Sigh. Okay, one second, reading again. (I'm sorry, pls. bear w/ me...)
From Time Traveler's questions I can tell he's trying to understand Hawking's 92 paper
unfortunate since my answer involved things from Visser's paper
Hawking's paper just used Misner space
It was a pretty vague conjecture
user228700
11:39
@JohnRennie Yes.
user228700
(Although, I will torture u another time, about how boiling relates to this, please rest assured :-P)
OK, what we've just proved is that if we hold the temperature constant and keep lowering the pressure then there is a pressure below which all the liquid turns to gas. For a pure liquid that pressure is the saturated vapour pressure.
Now let's consider what happens if we increase the pressure.
Once more start with my sample of pure B in my sealed vessel. So the pressure inside the vessel is $P_b$. Is that OK as a starting point?
user228700
@JohnRennie Okay, I think I finally understand. Phew. Okay.
user228700
@JohnRennie Yes.
OK, if I now compress my vessel the pressure goes up. Some of the vapour now condenses back into liquid so the pressuire falls back to $P_b$. Yes?
user228700
11:43
Yeah...
And if I compress it again the same happens, and again. As I keep compressing the vapour condenses into liquid to keep the pressure at $P_b$.
user228700
Oh God, the point I kept losing was the fact that at a given temperature, the saturation vapour pressure is constant!
But eventually all the vapour has turning to liquid and now the pressure starts to rise above $P_b$.
@Kaumudi aha, I suspect you've made the leap necessary to understand this :-)
user228700
:-) Okay. One moment...
user228700
Okay, will u be mad if I asked a dumb question again? Also, dyou have to go have lunch or s'thing?
user228700
11:50
Ah, it's only 11:50 AM. OK, does that mean that lunch comes a little later?
@Kaumudi I have to go out in about an hour, but I'm around until then. Ask your question - I bet it's not dumb :-)
user228700
Oh, I bet it'll (my question) piss u off :-P I'm asking about how, if we decrease/increase the volume of the container, won't its pressure have to be always equal to the surrounding pressure if it's a sealed container?
@Kaumudi @Kaumudi can you please tell me which book you are reading
user228700
@koolman Uhh, I will, if u tell me why u want to know so badly...
Mew
Mew
surround pressure?
do you mean surrounding the steal container?
11:54
@Kaumudi no because the container walls are rigid.
Mew
Mew
sealed*
After all, a diver's air tanks have a pressure higher then the surroundings.
Mew
Mew
well no because if it's say a glass container, there is no reason the inside pressure should be releated to the outside pressure at all
@Kaumudi because i want to also learn from that
Mew
Mew
@Kaumudi a balloon will tend to have the same pressure inside and outside
Because it's volue will change if there is a pressure difference (ignoring elastiicity for now)
but a steal container for instance won't move in response to pressurte differenc between inside and outside
so it is certainly possible for a container with strong walls (e.g. steal, glass etc.) to have differeing pressures inside and outside
user228700
11:56
@koolman Oh, well, you're not going to be able to buy it from the market :-| Its the material given by the institute Resonance.
user228700
@JohnRennie This. Okay, okay.
Mew
Mew
Remember pressure = F/A thus inward force on wall = internal pressure * area of wall
similarly external force on wall pushing inwards = external pressure * area
If the container can withstand force, there is no reason for these to be equal
@Kaumudi Cool. Where we got to is that for our pure component B if $P < P_b$ then it's all gas and if $P > P_b$ then it's all liquid. Are you happy this is a good starting point?
Mew
Mew
But a baloon will expand or contract until inward force = outward force
user228700
11:58
@Mew: Okay, thanks!
user228700
@koolman You're in 11th, right? I can give u my books next year, if u want them.
user228700
@JohnRennie Yep.
@Kaumudi thank you but i am in 12
Mew
Mew
@Kaumudi will u give me the books?
user228700
@koolman Ah, I see. Okay.
Mew
Mew
11:59
I would like to sell them on the market
user228700
@Mew xD I think I'll do that meself, sir!
@Kaumudi and of course the same applies if we have pure A. In this case if $P < P_a$ then all the A is vapour and if $P > P_a$ then all the A is liquid.
Anonymous
@koolman You can buy resonance books from their website...dlpd.resonance.ac.in
@Kaumudi can you send me the screen shots of that
user228700
@JohnRennie Right.
user228700
12:00
@koolman Of what? O.o
Only this topic
user228700
The whole chapter?!
@Kaumudi now suppose I put a mixture of 50% liquid A and 50% liquid B in my evacuated vessel. Suggestions as to what will happen?
Not whole chapter just things about phase diagrams
user228700
Dude, these books suck at explaining things properly. @JohnRennie knows exactly how much they suck. In fact, he is bearing the brunt of this "suckiness" :-P
Mew
Mew
12:02
@JohnRennie I have a physics question will you help?
@Slereah : A google search does indirectly (even if unsuccessful) diagnose something about a question. I agree with your comment under the question.
@Mew I think we've nearly sorted K's question. Can it wait a minute or two?
Mew
Mew
np
user228700
@JohnRennie Uhh, when we do what? If we change the pressure, u mean?
Well when we start with just liquid in our vessel both liquids evaporate until the vapour partial pressures are $P_a x_a$ and $P_b x_b$. That's what Raoult's law says.
user228700
12:04
@Mew Like I said before, @JohnRennie: Please consider cloning urself for the benefit of all students :-P
user228700
@JohnRennie Yes...
Because $P_b < P_a$ that means more B evaporates than A. So the liquid has a slightly decreased proportion of B and the vapour has an increased proportion of B.
user228700
Riight...
And the total pressure is $P_a x_a + P_b x_b$
user228700
Yes...
Mew
Mew
12:06
What is $x_a$
@Mew mole fraction of A in the liquid
user228700
@Mew Mole fraction of component A in the liquid mixture.
Mew
Mew
correct
user228700
—.—
@Kaumudi now suppose I expand my vessel as before. The pressure drops as I expand my vessel and both liquids start evaporating to increase the pressure again, just as happened in the pure liquid case.
user228700
12:08
Yes...
As before, more B evaporates than A.
And that means that the composition of the liquid changes.
user228700
Yes...
So if the mole fraction of B was $x_b$ before the expansion it is now $x'_b$ where $x'_b < x_b$. So far so good?
user228700
Yep.
And likewsie the liquid has become enriched in A so $x'_a > x_a$
user228700
12:11
Yes...
the pressure is now (Raoult's law again) $P' = P_a x'_a + P_b x'_b$
user228700
Yes...
But remember that $x'_b \ne x_b$ and $x'_a \ne x_a$ so the pressure has changed
user228700
Yes...
Mew
Mew
So Raoult's law only applies momentarily?
it is not an equillibrium result?
12:13
And this is the key difference between a mixture and the pure component. For a mixture the pressure can change while the liquid and vapour coexist.
Mew
Mew
oh sorry
I missed the "expand vessel" part
user228700
@JohnRennie Riight...
user228700
@Mew Huh?
Mew
Mew
WEll @JohnRennie said the he expands the vessell
and then he applied Raoult's law again. I initially didn't read that bit
@Kaumudi Suppose we start at a very high pressure, well above the vapour pressure of either component, then no vapour will be present because $P > P_a$ and $P > P_b$. Does that now make sense?
Mew
Mew
12:16
sup @heather
@Mew, hello
user228700
@JohnRennie Yep!!
Mew
Mew
hows pokemon goin
user228700
@heather: Ello :-)
@Kaumudi, hi =)
12:18
@Kaumudi Now we decrease the pressure until it is equal to whichever of A and B has the greater vapour pressure. And at that point if we decrease the pressure any more the more volatile component will start evaporating.
user228700
@JohnRennie Yes...
user228700
@S007: It seems that @koolman has followed ur footsteps and gotten into trouble (likely) at The Periodic Table.
Anonymous
@Kaumudi which footsteps ?
Which trouble @Kaumudi
And if we decrease the pressure further some of the less volatile component starts evaporating as well. Because the composition of the liquid is changing the total vapour pressure changes as well. So the pressure changes smoothly.
user228700
12:20
@S007 Go check for urself, I'm busy thinking about pressure :-P
Anonymous
@Kaumudi Leave, i'm too lazy
Anonymous
:-P
user228700
@S007 He pinged everyone :-P
user228700
@JohnRennie Ah, yes...
Anonymous
@Kaumudi Oh that? LOL :-D....
12:21
I don't suppose anyone would mind helping me with calculus?
especially integral calculus
@Kaumudi If I keep expanding my vessel the pressure keeps falling until all the more volatile component has evaporated, and at that point if I keep expanding the vessel all the remaining liquid will evaporate.
@0celo7, hello =)
Mew
Mew
@heather yeah bring it on
@heather Ask and see if they can help
user228700
@heather That's correct. Don't suppose such atrocities.
12:23
@Kaumudi, lol, okay =)
Anonymous
@Kaumudi Now, I want to give a lecture on evaporation and boiling, get ready!
user228700
@JohnRennie Yes, OK...
user228700
@S007 Nooo. My brain is effed up, man, leave me alone :-P I'll come back later tonight.
so basically, I've been trying to teach myself calculus, and I don't really understand how to use, i.e., the product rule for integration. Given a derivative, I can probably figure it out, given an integral, I have no chance basically of figuring it out, unless it is really simple, and I'm not sure why.
@Kaumudi, good luck with that exam btw!
Mew
Mew
is ur exam tmr Kaumu?\
user228700
12:25
@heather Thanks :-) Half the people here (including me) are writing the exam (next year) so good luck, everyone! :-P
@Kaumudi And that's what your original graph was showing you. At low pressures we have both A and B as vapour. At high pressures we have both A and B as liquid, and in between there is a range of pressures where we have some A and some B but the composition of the liquid and vapour are different.
Mew
Mew
@Kaumudi so no more questions after tonight?
@heather do you have some examples
@Kaumudi, oh, wow, that's nuts, studying a year in advance?
user228700
@JohnRennie Ah, I see...
@Mew, for instance, given the integral $\int^{12.5}_0 (50-3t)(9.8) dt$, I'm not sure what I'm doing
12:26
@heather I suspect you're thinking of revising rather than studying. After all, I started studying for my degree finals three years before the exam! :-)
Mew
Mew
@heather a constant can be taken out of the integra
user228700
Okay, I'ma have to read everything again but I'm pretty sure I'm on my way to understanding it properly.
user228700
@JohnRennie :-D Thanks, guru!
I started by doing $\int(50-3(12.5))(9.8) - \int (50-3(0))(9.8)$
user228700
@JohnRennie Lol, agreed.
12:27
because it is a definite integral
Mew
Mew
so that equals $9.8\int 50 - 3t dt$
Anonymous
@Kaumudi Okay, be ready for the lecture when me meet next time on h bar :-P :-D Bye for now!
@Mew, but I didn't think you could do that, because constants turn into 9.8x (for instance)
Anonymous
user228700
@S007 I wish you'd stop calling it "lecture". I'm still very sure that it's just a matter of miscommunication.
Mew
Mew
12:28
@heather you can still do it
@Mew, why?
Mew
Mew
i'll explain with simple example
Anonymous
@Kaumudi No, no. Let me preserve my ego :-P Bye for now :)
user228700
Because I understand where you're coming from @S007. Still, alright, alvida, for now :-)
Mew
Mew
$/int 2x dx$ = 2x^2/2 = x^2
also
hang on let me get the latex right
Anonymous
12:29
Alvida :-D
Mew
Mew
$/int 2x dx = \
@heather you're integrating $\int f(t)dt$ where $f(t) = (50-3t)(9.8)$. Just multiply it out to get $f(t) = 490 - 29.4t$. Then do $\int (490 - 29.4t)dt$
user228700
@Mew Are u kidding?! I'll stick around and pester anyone who wants to be pestered, don't u worry!
Mew
Mew
@JohnRennie, that is one way, but you can also take it out of the integral
@heather integral of 2x is x^2
The integral of x = x^2/2
@Mew @heather the point is that the same applies if you have e.g. $f(t) = (50-3t)(9.8t)$
Mew
Mew
12:31
thus 2 * integral of x is the same as integral of 2x
my point is $k\int f(t)dt = \int kf(t)dt$
Multiply out to get $\int (490t - 29.4t^2) dt$
Mew
Mew
for any constant k
@heather, an integral is a sum of small parts, you can take out any common factor
Imagine integral as an area under a curve, if the curve is multiplied by k, the area is multiplied by k too
$$\int u(x)v'(x)dx = u(x)v(x) - \int u'(x)v(x) dx$$

There are couple of integrals you want to use the integration by parts, such as if your integrand is a polynomial multiplied by an exponential.
e.g.
$$\int (x^2+x) e^x dx$$

Here you want to set your $u(x)$ to be $(x^2+1)$ and $v'(x)=e^x$, so that after using integration by parts, the power of $u(x)$ will decrease for each time you use it. Therefore after 2 iterations, the integral on the rightmost side of the expression will be just $\int e^x dx$ which is one of the easy cases. Thus
Hello, everyone! Can we ensure that the electromagnetic four-potential will always be timelike? Or, what physical conditions decide whether it will be timelike or spacelike?
@S007 @JohnRennie, okay. One thing I missed, though, in the videos I watched: what is $\int cx dx$ where $c$ is some constant?
Mew
Mew
12:34
@heather, another example. $\int 2 = 2\int 1 = 2*x $
insert dx behind each integral
$\int cx dx = $c\int x dx = \frac{cx^2}{2}$
Mew
Mew
yes you can take the constant out of the integral
so it iss $c\frac{x^2}{2}$
@Mew, wait, no, I thought $\int 2 = 2x+c$
Mew
Mew
yes
that si what i said heather
timeout typo: Previous message of mine should be $2e^x$ not $e^x$
Mew
Mew
12:35
I wrote $2*x = 2x$
oh, nevermind I missed the second equals sign
okay, so I factor out the constant, and get $9.8 \int^{12.5}_0 50-3t \, dt$
Strictly speaking $\int 2 dx = 2 \int dx = 2x$
Mew
Mew
@JohnRennie, strictly speaking = $2x + c$
don't forget the C for indefinite integrals
If you're integrating wrt $dx$ then any factor that doesn't involve $x$ can be taken outside the integral.
Mew
Mew
12:38
@heather, that's correct so far
so really you can take out 50 too
right?
Mew
Mew
no
Mew
Mew
because 3 doesn't have 50 as a common factor
but you can split the integral up into:
$\int 50\, dx - \int 3t \, dx$
Mew
Mew
12:39
$9.8\int 50 dt - 9.8\int 3tdt$
@heather integration is distributive so $int (f(x) + g(x))dx = \int f(x)dx + \int g(x)dx$
Mew
Mew
Now you can take out the 50 and the 3 if you wahnt
but the integral of 50 is so simple there is really no point
Mew
Mew
ype, or 50t rather in this case
* 9.8
Mew
Mew
12:40
yep
so the first term is 9.8*50*t
and the second term can be simplified to $-9.8\times 3 \int t dt$
$-9.8\times 3 \times \frac{t^2}/{2}$
right, that makes sense
Mew
Mew
that last bit is meant to be t^2/2
NB I thought when heather said integration product rule, is referring to the integration by parts. It seems I understood it wrongly
@Secret, I was, but this was one of the earlier problems I had trouble with before the integration product rule.
Mew
Mew
@heather, now that you have the answer, you must plug in the limits of integration
12:42
right
Mew
Mew
and go the top limit pluggin in mins the bottom limit plugged in
okay, let me work this out real quick
I got 8421.875
Mew
Mew
I got
3828.125
wow, that's not good
okay, let me do it again
I redid it and got the same result
Mew
Mew
Ok this is what I did
the solution to the integral is 9.8*(50t - 3t^2/2)
we need to evalute this for t = 12.5 and t = 0
when t = 12.5 we get
9.8*(50*12.5 - 3*12.5^2/2) =
3828.125
12:49
I started with $((9.8*50*12.5) - (-9.8*3*\frac{12.5^2}{2})) - ((9.8*50*0)-(-9.8*3*\frac{0^2}{2}))$
Mew
Mew
and when t= 0, we get 0
why the double negative?
why -(-9.8 ?
and then why did I put *12.5 in the first parens...
Mew
Mew
no everything is correct
except it should be only a single negative in front of the 9.8
oh, wait, I know why
11 mins ago, by Mew
and the second term can be simplified to $-9.8\times 3 \int t dt$
Mew
Mew
yeah
I was assuming first term + second term
thus I absorbed the negative in the second term
sorry for the confusion
12:52
yeah, and I wasn't, so I messed it up =) no, you're good, I should have realized it didn't make sense.
Mew
Mew
but yeah, just as constants can be taken out of integrals, so can a negative sign
okay, yeah, because a - sign is really -1
Mew
Mew
$\int -f(x)$ = -\int f(x)$
precisely
well thank you that helped a lot
could I have an integral to solve?
Mew
Mew
np any other questions?
ok
$\int 2x(2x^3 + 4x^7) dx$
12:57
=) here goes
Mew
Mew
oh and let's say the limit is from 0 to 3
okay
Mew
Mew
Also remember only constants can be removed from the integral
$x$ cannot be
okay
Mew
Mew
too hard?
13:06
nope just had to do something for my mom =)
Mew
Mew
awwww
i got -17301.6
got to go
Mew
Mew
laterz
@S007 @Secret I have posted an see ithttp://chemistry.stackexchange.com/questions/62882/azeotropic-distillation/628‌​87#62887
1
A: Azeotropic distillation

koolmanHere an answer for , I know it is bit confusing

Anonymous
13:22
@koolman good answer
13:35
Yeah that makes sense, so basically the vapor move towards the right and down and the residue move towards the left and up in the phase diagram
thus resulting in the pure A and the vapor B (which is the azeotrope)
13:59
@S007 this is because of your explanation
@Secret yeah
@Mew Hey Smithy, can you do me a favor?
Check over this code
Anonymous
14:21
@koolman :)
Anonymous
Keep asking your doubts whenever you have one :)
DHMO, MAFIA
[Division by zero]
Definition 1: Given a non annihilating semiring $S$, a left zero term is an expression $0a\neq 0$, while a right zero term is an expression $a0 \neq 0$. It is a two sided zero term (or just zero term) if it is both a left and right zero term. The order of a zero term is the power $n$ of the element $a$ (which can be zero).

Theorem 1: All left zero terms are idempotent in a left distributive semiring, while all right zero terms are idempotent in a right distributive semiring
Mew
Mew
@SirCumference wat is it bro
14:47
@koolman I don't know how exactly chemistry.SE sees it, but we don't like the posting of images in answers. First, you didn't give any source where you got that from, and second, images are not searchable for the text in them. If you can't be bothered to write an answer in your own words, don't write an answer.
[Division by zero] What I am suspecting is that these objects are mostly controlled by these idempotents (which has some absorbing properties), thus in a way they are similar to semigroups. This might suggest they can be handled using the framework of semigroup theory
@heather Here's a tip (I think @DanielSank also tried to give it to you yesterday, but I'm not sure he said it in a way you understood): When I look at your calculation steps, all I see is a bunch of numbers that means nothing to me, and I would have to dig up the problem itself to get what they signify. Writing e.g. $g$ instead of 9.8 and $t_0,t_1$ instead of what I think are the starting and end times makes your formulae a) shorter b) more readable.
At the very end, when you have simplified what you wanted to compute as much as possible, you can then plug in all the numbers again
Oh crap, wrong room, wrong person
Sorry haha

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