A non-relativistic radial wave function takes the form $R_l \approx \frac{\sin(kr - \frac{1}{2} l \pi + \delta_l)}{r}$ as $r \to \infty$ where $\delta_l$ is determined by the boundary conditions, what is a simple example where $\delta_l$ is determined
Deriving $e^{ikz} \approx \sum_l i^l (2l+1) P_l(\cos \theta) \frac{\sin(kr-\frac{1}{2}l\pi)}{kr}$ is no joke
If you think about it, you have to derive/remember spherical harmonics, you have to solve the spherical bessel equation, normalizing them properly, and you have to know their asymptotic approximations, all to express the wave equation for a free particle $e^{ikz}$ in terms of free solutions in spherical coordinates
Getting spherical harmonics from the ladder method takes ages and full of remembering huge expressions, the spherical bessel equation is absolutely not easy to solve without a trick whose origin made no sense for a long time
sometimes I am wondering, is there any situation that summing harmomic oscillators and spherical stuff gives a bad approximation. The world is surprisingly not only mathematical, but described really well in terms of oscillators
For spherical bessel with $l = 0$ you solve directly with the solution being $A\sin(kr)/r + B \cos (kr)/r$ (throwing away $B$ in the free particle case), for $l > 0$ you pull off a $r^l$ factor (can be motivated nicely) then the usual thing people tell you to do is to just differentiate the resulting equation and then magically on setting $\chi_{k,l}' = r \chi_{k,l+1}$ and expanding you will get back the $\chi_{k,l+1}$ equation with $\chi_{k,l+1}$ as the solution.
Yeah once you get the $\chi_{k,l}' = r \chi_{k,l+1}$ thing we immediately see $\chi_{k,l+1} = \frac{1}{r} \chi_{k,l}' = (\frac{1}{r} \frac{d}{dr}) \chi_{k,l} = ... = (\frac{1}{r} \frac{d}{dr})^l \chi_{k,0}$ (the minus is sometimes left out, should check this point now hmm)
Basically if you consider the $l=-1$ case you get the same solution as in the $l=0$ case except with no $1/r$ term and an overall minus sign so you immediately see this $(\frac{1}{r} \frac{d}{dr}) \chi_{k,l} = \chi_{k,l+1}$ assumption is very natural
In $\frac{1}{r} \frac{d^2}{dr^2} (r R_{kl} ) - \frac{l(l+1)}{r^2} R_{kl} + k^2R_{kl} = 0$ the $l = 0$ and $l = - 1$ cases knock out the $1/r^2$ term, yeah it should be $\chi_{k,l+1} = (-\frac{1}{r}\frac{d}{dr}) \chi_{k,l}$.
One interesting thing that came from looking at the $l = 0,m=0$ associated Legendre case $\frac{d}{dx}[(1-x^2)\frac{d}{dx}y] = 0$ was that $y = \frac{C_1}{2} \ln|\frac{1 \pm x}{1 \mp x}| + C_2$ (forget the signs, $C_1$ and $C_2$ being constants of integration) is the explicit solution, but it's not finite at $x = \pm 1$, so the $y$ should be a constant so it's derivative is automatically knocked out in $\frac{d}{dx}[(1-x^2)\frac{d}{dx}y]$
I recently asked and answered a question on the main site: What are the Energy eigenstates for a modified quantum harmonic oscillator?
First of all, this question ended up being re-tagged as homework, which I understand. While the question is not the sort of question addressed in even relatively...
so I have a natural magnet attached to a vertical ferromagnetic surface. How can I compute the horizontal and vertical magnitude of the magnetic force? Clearly they are easily determined experimentally, but what material property of the magnet determines the horizontal and vertical components?