ah yes, the point is simply that the quaternionic structure on $\mathbb{R}^4$ means we can find a canonical basis of the orthogonal complement $v^{\perp}$ for any non-zero vector $v$ by taking the rotation that maps $e_1\mapsto v$ and applying it to $e_2,e_3,e_4$. then, $V(2,4)=S^3\times S^2$ maps $(v,w)$ to $(v,v^{-1}w)$, where $v^{-1}w$ now lies in the unit sphere of $0\oplus\mathbb{R}^3\subseteq\mathbb{R}^4$.
now $(v,w)$ and $(v',w')$ span the same *oriented* plane iff they differ by a rotation in that plane, i.e. there is a $z\in\mathrm{Span}(v,w)$ s.t. $(v',w')=(zv,zw)$, but then these…