I don't know about properties, but here's what I was thinking of: consider the category whose objects are indexed tuples of vector spaces, $(V_i)_{i\in I}$, where $I$ is any set and each $V_i,i\in I$ is a vector space (over some fixed base field). A morphism between $(V_i)_{i\in I}$ and $(W_j)_{j\in J}$ consists of any map $g\colon I\rightarrow J$ and a linear map $f_i\colon V_i\rightarrow W_{g(j)}$ for each $i\in I$.
I feel this should be $\mathbf{Vec}^{\mathbf{Set}}$ in some sense I can't specify.