Given $p \in M$, $M$ a connected manifold, there is a map $\Omega_p M \to \Bbb Z/2$ sending $\gamma$ to the neutral element iff $\gamma^*TM$ is an orientable bundle over the circle. Then we have the following properties.
1) This is a group map: if you compose two loops, then $(\gamma_1 \ast \gamma_2)^* TM$ is orientable iff $\gamma_1^*TM$ and $\gamma_2^*TM$ are either both oriented or both unorientable. This requires a little understanding of bundles over the circle. In particular, the map on $\pi_0$ is a homomorphism $w: \pi_1 M \to \Bbb Z/2$.