Let $\cdot : \mathbb{Z}\times \mathbb{Z}\rightarrow \mathbb{Z}$ be the usual multiplication and let $n\in \mathbb{N}$.
To show that $[a]\cdot_n [b]:=[a\cdot b]$ defines a concatenation of $\mathbb{Z}/n\mathbb{Z}$, we have to show that $[a]\cdot_n [b]\in \mathbb{Z}/n\mathbb{Z}$ for all $a,b\in \mathbb{Z}/n\mathbb{Z}$, or not?