@pentavalentcarbon I see where you're coming from and I think I made an implicit assumption that a book would be more like a reference work, which was maybe a bit influenced by my own reading patterns. With something like a coffee table book, though, my concern is still the target audience. You would be marketing to... casual readers of specialised information (hardcore readers will go for the textbooks, laymen will go for popular science).
I'm not saying such a group of people doesn't exist, but it just strikes me as weird, because I would have thought that the Internet was the natural medium for that, not a book.
Anyway, it's a rather tangential discussion, which is why I don't really want to respond in the comment section. And if we agree that it probably won't work then it's sorta moot anyway
@Abcd you've a lot of unaccepted old questions on both the main and meta; just a nice reminder that you may wish to accept answers to a few of them :)
There used to be a place on the internet where you could enter compounds and things such as acidity constants were calculated, including which proton deprotonated in which order. Alas, I can’t find the site any more. — JanNov 21 '17 at 14:31
@orthocresol do you know what website Jan is referring to?
You were absolutely correct when you said that nitrosation takes place.
What actually happens is that after nitrosation occurs, concentrated $\ce{HNO3}$ oxidises the nitroso group to form nitrobenzene.
Source
A Guidebook To Mechanism In Organic Chemistry; Chapter 6, section 6.2;Peter Sykes
From Clayden (Chapter 37 Rearrangements page 976):
Intramolecular reactions (including participation of a neighbouring group) that give three-,
five-, or six-membered rings are usually faster than intermolecular reactions.
It also gives the exact same example as your question:
...
@GaurangTandon There are not many people conversing on earth science chat. Maybe, the question has more chance of being answered here due to more traffic.
I dare you to find an advanced chemistry textbook that does not contain the topic electrophilic aromatic substitution. Have you found it? name the title.
Though I'm still not comfortable with that NGP question, so I'll leave it open. Please don't mind, I may come back later to detail in your answer itself, but I don't have the time right now
CIP rules for cyclic substituents are different. See
this question for the rules. (The rules are given in the question itself).
This will be the hierarchical digraph for the right side of the molecule.
The atoms encircled are the ghost atoms. From the digraph one can see why the compound is...
Your generation of electrophile is correct the subsequent primary carbocation formation by the attack of electrophile is incorrect.
In my second step, that particular carbocation is formed since $\ce{Ph}$ is an electron-withdrawing group.
The benzene ring stabilizes the carbocation th...
Are there any computer programs or online resources that could help me figure out whether the reaction will take place or not, and if yes, at what temperature?
Long version of the same question:
I am starting to learn chemistry. I found a video "The Laws of Thermodynamics, Entropy, and Gibbs Fre...
Why are phosphonate-stabilised ylides used in HWE reaction more nucleophilic than phosphonium ylids used in Wittig reaction? Explanations without rationalisations using d orbitals would be welcome.
On sites like CrossValidated (but I guess this applies also to the math sites etc.) we often have users who post math formulas as pictures, rather then using TeX formatting that is supported by the platform. Some of the users are unfamiliar with TeX, some just lazy, yet it would be nicer to have ...
@GaurangTandon, just a heads up that that RE60K guy was highly disruptive/rude/antagonistic when he was still active. He got suspended for a very long period of time and doesn't seem to want to ever come back (just as well). Not that you did anything wrong, but just something that may/may not influence your actions on his posts/comments...
@Martin-マーチン Thanks. This community has become crazy. This year whenever I asked anything, my question was downvoted or even closed. And I can see many good questions (asked by other users) downvoted. This community is no longer like what it was a few years back. A few years ago no one downvoted my question and my questions were never closed. This year, even my old questions were downvoted by some people. I can see some crazy people, and even administrators who know nothing about chemistry, have come and taken power. I'm ready to close this account since the platform is no longer friendly. — Alright8 hours ago
Probably what happened is as the rate of bad questions appearing has increased over the past few years, some of the negativity has carried over. On the other hand I don't see any of their questions closed, and most people don't understand what a downvote actually means.
Yes, the first part of the comment was heavily exaggerated. One of their 2018 questions received some downvotes, and this one was initially closed, but all are net positive score and are open. The second part is a bit silly, and at first I told the person off, but figured it would just be easier to nuke the comment, which had received an R/A flag (quite rightly so).