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8:15 AM
Hey anybody active
 
@satyatech hi
 
Can you answer a question@Fawad I will post right now
It's an easy but I have doubt
Qn no 46) mate nothing is given ,no temp ,no concentration ,how to do this
@Fawad can you answer
@skillpatrol can you answer
@orthocresol can you answer
Sorry for multiple pings but it's urgent i need the answer fast,plz get it
 
8:35 AM
@satyatech what Kp value you got?
It should be =25
 
KP=2.5 is what I got
@Fawad
 
Thanks @Fawad
 
 
7 hours later…
3:30 PM
Wow, I'm gone for a couple of days and I already don't recognize people in this room
Hey @Faw
 
@M.A.R. hi ,I want to make sure you people know iam old "Ramanujan"
 
@satyatech Please don't ping multiple people
@Fawad Ahh
Anybody know a set of good exercises for proton NMR? CC @Jan. I'm thinking of spectroscopic data of some compounds so I would identify the heck out of them
 
@M.A.R. Do you have access to textbooks?
It has very good exercises. (Any of the older editions is fine too)
 
3:52 PM
hi everyone!
 
Hi!
 
4:08 PM
Hi
 
@DSVA \o
 
 
2 hours later…
Jan
5:52 PM
@M.A.R. All I could reasonably do is present you PDFs of some nice compounds to identify along with the sum formula … ^^'
 
Slaps Jan
 
Jan
Ouch .___.
*hides in the cuddly, fluffy, pink corner*
 
6:06 PM
Reminder: We have a Be Nice rule, that is enforced. — Oddthinking ♦ Feb 8 at 16:36
Anyone else wonder what comments were deleted making a mod to type such a thing?
 
Can somebody help me in this
According to me it should be 6:1 as (36:216) , but the answer given as 3:1
How ?
 
Does methane burn in water?
 
Jan
@M.A.R. Na, it’s DonTrumpSays.SE; considering how fiery the emotions can turn when it comes to politics, I’m rather happy that I don’t have to see the deleted comments ;)
 
@CowperKettle An enthalpy change of plus 216 kJ/mol says otherwise
@user123733 Did you balance the equations?
@Jan That just sounds like you DO want that
 
@M.A.R. oh I got my mistake
Thank you
 
6:20 PM
Yay
NP
 
6:38 PM
@MaxW how can i find out if they are the same ? i was told that if two isomers are different they will have different names so now that this rule is no longer useful , how can i know whether or not two isomers are different from each other ? — Sam19KY 2 mins ago
This became harder than expected.
 
Oh shoot
it************** — Sam19KY 34 mins ago
Hehe
When did our site turn to SO?
I feel like talking to cave men.
Loong hoola hola hola holloola
 
6:58 PM
Man, these posts are awesome.
I especially like this part:
> Cut to the current election. We had heard allegations that Trump kept Hitler’s speeches by his bedside, but somehow we normalized that. We didn’t take him seriously because of all the outrageous, clownish acts and gaffes we thought would cause him to drop out of the race. Except these gaffes were designed to distract. This was his secret strategy, the essence of his success — you can’t take a stand against Trump because you don’t know where Trump is standing. You can’t find him guilty of evil, you can’t find him at all. And the tactics worked. Trump was not taken seriously, which allowed
 
7:12 PM
I love it if people ask questions and after they get an answer they are all sassy about it...
 
@DSVA Examples?
 
@DSVA That happens when they drink too much butanol.
4
 
Ahh, DSVA is from somewhere called Ostrich
 
-1
Q: Why n-Butanol is not used as a safer alternative to ethanol in the alcoholic beverages?

aiagThe $LD_{50}$ of n-Butanol adjusted for its intoxicating potency is about 1.5 times that of ethanol. This would mean to me that n-Butanol is therefore 50% safer than ethanol. Why is it not used to replace ethanol in the alcoholic drinks?

@Loong yeah I guess so^^
 
@DSVA Where is Ostrich located?
And what do you think of my Romanization?
 
7:18 PM
where does it say Ostrich?:-D
@M.A.R.
 
@DSVA Your profile does
 
Oh, for me it says "Wien, Österreich" which is Vienna, Austria
 
Ah well, close enough
 
I guess it translates to Ostrich in some languages?
 
Nice, I learned a potentially Austrian word.
Which is a word for . . . ''Austria''
 
7:20 PM
well, german-stuff is a tag here so nothing wrong with german words here I guess:-D
 
Are there great differences between what would constitute Austrian and German?
 
@M.A.R. similar to british and US english I guess
 
Jan
Contrary to what Einstein may say, God throws a die. — Jan 12 secs ago
x3
 
Ugh, so what's Bavarian then? Martian English?
@Jan Throwing dies is dangerous
 
7:23 PM
oh that's it own special thing:-D
 
@Jan Also, is this a badass analog to ''because Chemistry''?
Re-ping
 
Jan
@M.A.R. It is, but in a more physical way.
 
Yuck, physical
 
Hm, blackcurrant contains butanol. We could try that.
 
 
1 hour later…
8:44 PM
@gannex ^ Hmmmm...
 
Jan
@orthocresol Right when I was editing that post to include MathJax D=
 
Yeah...
 
Jan
9:00 PM
I’ma badassy day today
The terminal $\ce{B-H}$ bond is 15.7 terminal arbitrary units strong, the bridge-$\ce{B-H}$ is 3.14 arbitrary bridging units strong. (Hint: there is no commonly accepted definition of ‘bond strength’.) — Jan 13 secs ago
Wow …
This question is about a 1.2 on the Mohs scale; not actually hard. — Jan 13 secs ago
 
 
2 hours later…
11:32 PM
@orthocresol You didn't know about those transition mentals?
question for the chat: does anyone know how exactly OCl- oxidizes the TEMPO radical?

as in this mechanism:
http://www.sigmaaldrich.com/content/dam/sigma-aldrich/articles/Chemistry/tempo-catalyzed-oxidations/tempo-mediated-oxidation-of-alcohols.jpg
 
Jan
No one is asking how this is supposed to be done. You seem to be engaged in stalking now. Please leave, I do not want or need anything from you. — aiag 39 secs ago
Laugh of the day :D:D:D
 
@Jan thanks for editing my answer there. Very nice. I guess I was being lazy.
 
Jan
@gannex Which one of the many I edited today? ^^'
 
@jan it was my answer about ligand exchange mechanisms. You typed a whole bunch of equations
 
Jan
Oh that one ^^
 
11:46 PM
I was being lazy and using photos of a textbook
 
Jan
No worries, I was just procrastinating my cleaning and sending away an application ^^
 
my answer was a procrastination on my midterm studying
while I have your attention@Jan , do you understand how the oxidation of the TEMPO neutral radical occurs swith NaOCl?
 
I'd guess single electron transfer?
No clue.
 
Jan
Oh sorry, I didn’t state that I don’t have any clue ^^'
I’m really not good at those SET mechanisms …
 
ooooh
I get it
you have to put an X- in with it
OCl- -> Cl- and O gives 1 electron to TEMPO while being attacked by the bromide... so that's why you need the KBr co-catalyst.
@Jan what's SET?
 
Jan
11:52 PM
@gannex Single Electron Transfer
 
oh
I understand where the electrons are going, but can this even be represented formally with arrow pushing?
 
Jan
Probably, but I can’t do it
 
@Jan could you drop me a ping if he comments again without tagging me?
 
Jan
@Jan Read this as ‘So I should be learning it in the next few weeks. Definitely!
 
Oh, nevermind: I just saw it.
12 year olds are edgy
 
Jan
11:54 PM
If I hadn’t just been in chat I wouldn’t’ve seen it for like five minutes ;D
 
anyways, thanks for making my answer like neat and tidy
 
Jan
@gannex *bows* Glad that I could be of assistance
 

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