"I looked into this a week ago and from what I can see the big deal with toner is 1. how it's made - either it's been milled (crushed from big blocks using big rollers) or grown chemically. Milled toner has lots of sharp edges on the toner as the crushing rollers tend to leave sharp edges, where chemically made toner tends to be like little smooth surface spheres.
One slowly grinds against the insides of your printer, the other is much nicer to it."