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11:19
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Q: Are there any natural examples of this algebraic structure?

Smiley1000Define an exponential ring to be a set $X$ together with a collection of subsets $X_n$ for $n \in \mathbb{Z}$, elements $0_n \in X_n$, $1_n \in X_n$ and maps $+_n: X_n \times X_n \to X_n$ and $\cdot_n: X_n \times X_n \to X_n$ such that: $(X_n, 0_n, 1_n, +_n, \cdot_n)$ is a commutative ring $X_{...

What motivates this notion?
There is a constant (up to iso) sequence with $X_n\cong\Bbb Z_2\times\Bbb R$.
@coisco Ah, because $\left( \mathbb{Z}_2 \times \mathbb{R} \right)^\times \cong \mathbb{R}_{\neq 0} \cong \mathbb{Z}_2 \times \mathbb{R}$
@coisco That's nice, if you want to add this as an answer, I will accept it.
In your example we actually have $X_3=X_2$ as all elements in the zero ring are units.
@coiso This is an answer to the question, not just a comment. Please notice that comments should only be used to clarify, not answer the question. See How do comments work for more information. Therefore, I suggest to post your answer as an answer. This has many advantages, for example this brings extra visibility to the answer und puts the question off the unanswered list.
11:19
@SeverinSchraven Oops, you're correct! So the constant sequence $0$ is an exponential ring. Actually, this is probably the terminal object.
@Smiley1000 If there is an justice, then that should be true :)
Actually, it's now interesting to me what the initial object of this category looks like. But I don't want to move the goalpost, so I might ask this separately.
@Smiley1000 Isn't the sequence of zero rings also an initial object?
@SeverinSchraven I don't see how. For example, what would be a morphism to the example given above with every $X_n \cong \mathbb{F}_2 \times \mathbb{R}$? A homomorphism is at the very least a levelwise ring homomorphism, but there is no ring homomorphism $0 \to \mathbb{F}_2 \times \mathbb{R}$.
@Smiley1000 My bad, I was thinking of the category of rngs. Of course unitality destroys my claim.
@Smiley1000 Do you want $n\in \mathbb{Z}$ or $n\in \mathbb{N}$?
11:20
@SeverinSchraven I think having $n \in \mathbb{Z}$ is more entertaining
@Smiley1000 Do you know a ring which has cyclic group of units then?
@SeverinSchraven You mean a ring $R$ with $(R, 0,+) \cong \left( R^\times, 1, \cdot \right)$? Well, $R = 0$ does the job, and as said above we can also use $R = \mathbb{F}_2 \times \mathbb{R}$. I think the latter example is rather interesting.
@SeverinSchraven Or do you mean a ring $R$ with $(R^{\times}, \cdot) \cong (\mathbb{Z}, +)$?
@Smiley1000 The later.
@SeverinSchraven There is an example given here: mathoverflow.net/q/75192/155881 . This is essentially the group ring $\mathbb{F}_2[\mathbb{Z}]$. I don't think this gives the initial object, though.
I think math.stackexchange.com/questions/93409/… is highly relevant here. The ticked answer and comments thereunder show how to construct groups that could not serve as $X_0^\times$.

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