18:42
Well, sorry, but if something is random (or even if it is not), then it follows a distribution, as that is mathematically what it means for something to be random
The word "random" has no formal meaning except that
But your question was not how we can know that there is a distribution, you asked about how we know it obeys that distribution in the long term over many samples.
In my experiment, I only rolled the dice once each.
Although, even if you doubt that randomness exists in the universe, the mathematical theory of probability still applies to situations of imperfect information, for example people can still play Poker in a deterministic universe and make bets which they can determine to be profitable in the long-run, as long as it's assumed that neither player knows what the unseen cards will be
If you don't believe that the dice are fair or that they maintain their distribution in the long term, simply take the distribution for one roll and label the probabilities of each outcome p_1, p_2, p_3, p_4, p_5, p_6, then q_1...q_6 for the second die. Add p_7 and q_7 for the probabilities that the dice will respectively fall without a clear result, collapse into a black hole, or any other outcome than a number from 1 to 6.
Disregard all notions that these probabilities apply to any future rolls beyond the one roll I am about to make. Suppose that if I were to roll them a second time (which I will not do), the probabilities would be wildly different.
If you believe the dice are deterministic such that the outcome "3 and 5" is preordained, then these distributions still exist, it's just that p_3 = 1 and q_5 = 1 and the rest are 0.
If you believe the dice are deterministic but you don't know which outcome is preordained, then these numbers represent your subjective judgement of how likely each outcome is, or your best estimate according to a simulation, or whatever.
Whatever you believe, these numbers exist, even if nobody knows or agrees what they actually equal. And those numbers are a probability distribution.
Then the numbers p1q1, p1q2 + p2q1, p1q3 + p2q2 + p3q1, and so on, are another probability distribution. And there is no physical entity corresponding to that distribution.
So it follows that a probability distribution can be associated with a physical outcome but not correspond to a physical entity.