But finally I got the answer to be $\ln 2/2$ instead of $\ln 2$; The problem is entirely simple, and my answer varies from the correct one by a factor of $2$.
@JohnRennie Ok sir. I can see where I went wrong. But could you explain why a simple substitution of $V=iR$ makes the situation different. I'm unable to understand this point.
At time zero the voltage across the capacitor is zero because no charge has flowed onto it, and that means the whole voltage $V$ is dropped across the resistor. So the current at time zero is $I_0 = V/R$.
So you need to write down the power delivered by the battery, and this is the battery voltage times the current through the battery. This is true regardless of what the battery is connected to.
If the battery EMF is $E$ then the power produced by the battery is always $P = EI$. But for real batteries some of this power is dissipated in the battery due to the internal resistance $R$.
@JohnRennie In a problem, I saw internal resistance of a battery varies with the fact whether it's charged or discharged. I asked this question on the main site. And I got some answers indicating the conductivity of batteries vary depending upon the electrolytic composition. If it's discharged it's resistance is higher because it contains less number of charge carries. If this is so, will it not alter the potential difference of the battery? If so does a 1.5V battery would become a 0.5V battery
after usage. Then it seems the fundamental definition of battery fails - "a battery maintains a constant potential difference in a circuit"
In electrochemistry, the Nernst equation is an equation that relates the reduction potential of an electrochemical reaction (half-cell or full cell reaction) to the standard electrode potential, temperature, and activities (often approximated by concentrations) of the chemical species undergoing reduction and oxidation. It was named after Walther Nernst, a German physical chemist who formulated the equation.
== Expression ==
The Nernst equation is derived from the standard changes in the Gibbs free energy associated with an electrochemical transformation. For any electrochemical reducti...
The Nernst equation tells you how the EMF of a cell varies with the concentrations of the reagents.
As a battery runs down the concentrations of the reagents in the battery changes, so the battery EMF also changes according to the Nernst equation.
:-) That's why there wasn't anyone on the main site to answer that part. Yes sir. But I don't have a potentiometer and also some patience to eat away a fully charged battery.
> Car batteries have to be almost 'flat' (no energy left) before they won't turn the starter-motor, and an appreciable internal resistance would prevent them from doing so. This paragraph, though, is merely speculative.
Sir, if possible could you explain the above paragraph? I asked the answerer but still didn't get it.
> Figure 6: Typical internal resistance readings of a lead acid wheelchair battery. The battery was discharged from full charge to 10.50V. The readings were taken at open circuit voltage (OCV).
Yes sir. Thank you for sharing the website. It seems the internal resistance rises exponentially and I guess there is a minimum potential below which a battery is of no use. So even a battery completely dead - say our mobile phone's battery has some potential difference - say 2V if it's initially 100V. Am I right, sir?