@0celo7 You implicitly require $U \cup V$ to be the whole space? That's impossible in a connected space. But if you don't require that you could to something like $U=[-1,0)$ and $V=({1\over 2}, 1]$ in $[-1,1]$ with the standard topology.
$$ T = \{ \varnothing, \{a\}, \{b\}, \{a,b\}, \{b,c\}, \{a,b,c\} =X\}$$ with $U = \{a\}$ and $V=\{b,c\}$. Then the closure of $U$ is $\{b,c\}$ so they are not disjoint.