.. @BrunoStonek The canonical map p: X_{hG} = EG x_G X -> X/G gives rise to a Leray spectral sequence (constructed for instance in Segal's
Classifying spaces and spectral sequences, Proposition 5.2), with E_2^{p,q} = H^p(X/G,R^q p_*(Q))$ converging to H^{p+q}(X_{hG},Q). The stalk of R^q p_*(Q) at the orbit [x] is H^q(Stab(x);Q), so the spectral sequence is concentrated in the line q = 0 and the edge homomorphism corresponding to H^*(X/G;Q) -> H^*(X_{hG};Q) is an isomorphism.