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05:52
@JohnRennie: Hi sir. Good morning :-)
Do you remember how to determine the relative stabilities of resonance structures when some structures obey some rules and defy others?
Or in other words, is there any order of superiority for the four rules to determine the relative stabilities?
06:36
@GuruVishnu hi, sorry, I've been busy trying (and failing) to fix a server.
@JohnRennie No problem sir. Please take your time :)
I have no idea about the resonance structures I'm afraid. My memory or organic chemistry is virtually non-existant.
Ok sir. I'll ask it on Chem.SE. I was afraid to ask there initially, as I got comments criticising the concept of resonance stating that it's outdated.
Even if it's outdated we're supposed to learn them.
@JohnRennie: May I know why servers are unstable? Or what causes them to crash?
07:04
@GuruVishnu in this case something locked up the disks and that crashed the server. But I cannot work out what caused it.
"something"=virus or malware?
Or is it related to power fluctuations?
07:32
No idea at the moment ...
It has crashed two days in a row with the same problem
08:01
Hmm...
Ok sir.
 
7 hours later…
14:33
@JohnRennie: Hi sir. Kindly reply when you find time. Thank you.
Few days ago, we discussed about the rotational barrier of a triple bond. I liked the following explanation of yours:
in Problem Solving Strategies, Jan 14 at 11:14, by John Rennie
Although I'd expect the barrier to be lower than a double bond because with a triple bond it only takes a quarter turn to recreate the bonds rather than a full turn.
But, now I realised, that "quarter turn" isn't possible due to different in phase of the orbitals. So will the final outcome change or will it remain the same?
Earlier, I understood this based on the following image (without the indication of different phases)
Now, it seems the "cylindrical symmetry" will not hold true. I think due to difference in phases, there will be two half hollow cylinders with opposite signs.

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