I have at least two structures. I know there's at least one homomorphism between them, problem is: i don't know anything about the properties of said homomorphism, or even how many they are . . .
So . . . i want to know about the properties of said homomorphism but don't know what to do . . .
Much less can construct even one . . .
Essentially they are order homomorphism between a partially ordered set with a particular algebraic structure and a totally ordered set with the same algebraic structure . . .
And I need to know not just the nature of the binary operation, but actually the definition of the two specific structures you're talking about. Knowing only that they have this kind of structure and that one is totally ordered isn't much to work with. Not knowing anything about the category of these objects generally, there's no category theoretic trick that's going to save us any work.
Since it doesn't sound like the ordering operation and the addition interact (at least not that you've mentioned) you could always just look for monoid homomorphisms and then see if they preserve the ordering. But in general it sounds like you could easily end up with pairs of objects between which there are no homomorphisms.
Actually, not a counterexample. Probably just an explanation of why you have at least one silly morphism between these structures.
I was going to say take the natural numbers under their usual ordering and monoid operation; then take the structure with the natural numbers, their usual monoid operation, but the reverse ordering relation. But there's exactly one morphism between these structures: a homomorphism that maps everything to zero.
I.e. the zero morphism is always order preserving and a monoid homomorphism.