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2:55 AM
 
3:33 AM
 
4:10 AM
 
 
2 hours later…
6:02 AM
@JohnRennie Sir r u there?
 
6:12 AM
@user586228 hi :-)
 
Hello:-)
Can you touch upon the first problem
 
I can't help with the first problem.
 
Ok no problem
Can you help with the last?
 
The second problem is presumably related to the rate of heat conduction from the metal sphere to the air. I can see in principle how to do it, but it looks a hard calculation. I'd guess engineers have a simplied equation for doing it.
The last question is easy because you just have to calculate the volume per iron atom.
 
Can u targent the third first
Ok
Why not the entire cell?
 
6:18 AM
The FCC unit cell contains four atoms while the BCC cell contains two atoms.
 
ok
So the total volume
should remain unaffected ..Isn;t it?
 
In the BCC phase the cell is 0.293nm and it contains two atoms, so the volume per atom is 0.293³/2 = 0.0126nm³
 
In the FCC phase the volume per atom is 0.363³/4 = 0.0120nm³
 
ok
Now which minus which?
 
6:23 AM
So the percentage volume change is (Vf - Vi)/Vi = (0.0120 - 0.0126)/0.0126 = -4.9%
 
Answer is right
Now please tell me the phenomenon that occurs
How would the volume per atom change
Explain the mechanism slightly please..
 
There isn't a simple answer to that. It happens because the length of the Fe-Fe bond changes slightly when the phase changes.
 
Why did you not target the who cell
Why per atom
Please explain this to me.
 
Because if you have a lump of iron it has a constant number of atoms in it
 
ok
So...I still do not understand
 
6:27 AM
The total volume of the lump of iron is the number of atoms (which is constant) times the volume per atom.
So it's the volume per atom that we need to know.
 
Kind a because you do not know the totalatoms..??
Is it??
Or am I incorrect
Like dividing to have an intensive quantity?
True??
 
It only asks for the percentage change.
 
Ok...Is my observation correct?
 
If there are N atoms and the volume per atom is v, then Vi = Nvi and Vf = Nvf
The percentage change is (Vf - Vi)/Vi = (Nvf - Nvi)/Nvi and the N's cancel so we get (vf - vi)/vi
So we can just calculate the percentage change in the volume per atom.
 
How are you so sure that the N's are same
Please explain
It could be different for BCC and FCC also after the phase change
Why are they same?
 
6:33 AM
It's just a lump of iron. How can the number of atoms change when you heat or cool it?
 
Ok got you mole balanced
Now problem 2..Please get back to this one..
 
There will be some quick method engineers do for this. Trying to do it from first principles would be a complicated integral that I can't do.
 
@JohnRennie I have ample time
I do not regret if yo derive it from
First principles
 
6:54 AM
@JohnRennie Sir atleast tell the thinking process for the second problem if possible .I will figure out the rest myself.
 
@user586228 at some time t you have a liquid drop of radius r(t) that is less than the radius of the drop R, so there is a shell of solid iron of thickness R-r(t) around the liquid core.
The liquid is at 900K and the outer surface of the shell is at 300K (because it's cooled by the gas) so you have a temperature gradient of 600K across the shell.
From this you can calculate the rate of heat flow, dq/dt, and rate of solidification is the rate of heat flow divided by the latent heat of fusion.
And from the rate of solidification you can calculate the rate of decrease of the radius of the liquid core.
 
 
7 hours later…
2:31 PM
@JohnRennie Sir this is what I have been told about the problem.
Always start with

In - Out + Generation = Accumulation

Out = Area*h*(T-Tair)*t
Gen = V*density*Hfusion
Somebody told me this
Even then I am not getting the answer
Any help in the direction is welcome
@JohnRennie Sir I need it soon tbh :-)
 
 
2 hours later…
4:52 PM
Hello @JohnRennie sir
 
@PrateekMourya hi :-)
 
Sir a spring connected to a piston which is over a ideal gas
Initially the spring relaxed
The temperature is increased slowly
When spring stretched by x
Find work by gas
Sir here at every instance
How can we assume paiton to remain equilibrium
Piston
 
Let me draw a diagram ...
 
Ya big fan of your diagrams
 
This is what I think it means.
 
4:59 PM
Yes
 
The gas starts out at 1 atm and the spring is at its natural length. Then we heat the gas and the pressure goes up, so it exerts a force on the spring and compresses the spring.
 
There is an easy way to calculate the work done, since the work done is the work done on the spring i.e. the work done is the change in PE is the spring ½kx²
 
Yes but why piston remains equilibrium
 
Why would it not remain in equilibrium?
 
5:03 PM
Because we don't know nature of increasing force
What increases in which way
Why would gas force increase such that spring force too increase same way
 
You mean if it expanded fast the expansion would be irreversible?
 
Know suddenly one of force would increase much more than other
And cause u equilibrium
 
OK, suppose the piston has moved a distance x, then the tension in the spring is F = kx. Yes?
 
Yes
Is it us who increase temperature such a way that piston remains equilibrium
 
The force on the piston due to the pressure in the gas is F = PA, where A is the area of the piston.
And for the system to be in equilibrium this force has to be the same as the tension in the spring. So we must have PA = kx.
 
5:07 PM
Why this force has to same
I mean it doesn't increase
Such way that it balance spring force
When we released ablock connect to spring gravity would pull it
It would oscillate
 
The cylinder is heated, so the pressure increases. That's why the pressure goes up and balances out the spring tension.
 
Will it every time increase in such a way that its forces exactly to the spring force
 
We start with no pressure in the piston and no tension in the spring so everything is in equilibrium. Yes?
 
Then we slowly heat the piston.
 
5:11 PM
Ok
 
As the temperature increases the pressure increases and it exerts an increased force on the piston. That pushes the piston out until the force due to the spring compression balances the force due to the increased pressure.
 
Yes
More the force more compression
Since spring opposes it change in length
 
Yes
 
But its not relatable to the spring gravity system
Where the force of gravity continuosly pull
 
I don't see why gravity is involved here ...
 
5:16 PM
In some cases
Spring force is not always balanced
 
I think we would need to consider a specific question to go any further with this.
 
A block attached to spring is released
Find maximum velocity of block
 
Can you post a picture of the question?
 
I would need 5 mins
To go to my workplace
Its bit far away
Can you wait sir?
 
The trouble is that you are posting very vague questions with no details.
If you want to go and get your book or whatever so you can post the actual question then I'm willing to wait.
 
5:30 PM
Block is released under gravity
Here spring force is not in equilibrium
Every time
 
OK. The spring starts at its natural length so the tension in the spring is zero.
When you let go of the block it accelerates downwards until the spring tension is equal to mg.
At this moment the net force on the block is zero and the block has reached its maximum velocity.
Then as the block continues moving downwards the spring tension is greater than mg so the net force is upwards and the block graually slows to a halt.
Then when the block has slowed to a halt it starts accelerating upwards agaon.
@PrateekMourya OK so far?
 
Ok
Y
es exactly
Why doesn't this happen in case of the piston arrangement
Earlier
The pressure increases so the spring compress till it balance pressure force
But since piston gains velocity
It stretches more
 
I assume the piston and spring are on their side on a smooth surface.
Though I'd need to see exactly what the question said to be sure.
 
Why doesn't this happen
This is the exact problem
 
It says the piston is massless, so there is no gravitational force on the piston. That's why it doesn't fall under its own weight.
 
5:40 PM
Why doesn't the pressure of gas
Outweigh
The spring force
Jsut like gravity did
 
Earlier in that problem
@JohnRennie this case
 
@PrateekMourya in that case the block was not zero mass.
 
I see f=ma
M=0
F=0
Is this the principal?
 
Yes
 
5:45 PM
If it had would it also be in equilibrium
Same as massless one
 
So the only forces acting are due to the pressure of the gas and the tension in the spring. The weight of the piston is zero.
 
Sir are you here?
No problem i will discuss tomorrow
Atleast the particular case is clear
 
@PrateekMourya Hi, yes, I'm still here.
But I've lost track of what you are asking.
I need to go now. I'll be around tomorrow as usual.
 
6:25 PM
@satan29 yea I was attempting past year papers online and I got bonus there.. . .
 

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