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1 hour later…
2:56 AM
@GaurangTandon Probably because they're not particularly reputable.
 
3:16 AM
@orthocresol hmmm
 
 
5 hours later…
7:59 AM
@Loong may I ask the motivation behind: "You should also not rely on chemical catalogues (e.g. Sigma-Aldrich) or online databases (e.g. ChemSpider)."? (src)
do you intend to convey that they often generate incorrect names?
 
Yes, such sources sometimes tend to use the traditional names that have been frequently used in the past (e.g. in literature) but don't necessarily promptly follow the changes in IUPAC recommendations or are not updated at all. Thus, if you want to be sure that a name is in accordance with the current nomenclature recommendations, better don't rely on such sources. However, the names are not necessarily incorrect.
 
okay, thanks!
@Loong "better don't rely on such sources." I'll rather rely on Loong ;)
 
Always check yourself if you want to be really sure.
And also note in that meta post:
> These guidelines are meant to be recommendations, not absolute rules.
 
aye aye
 
8:14 AM
Need help
@Loong Can u share with me some properties of partial derivative that
we use in chemical thermodynamics
I dont understand chain rule and stuffs in such partiial deriavtives...
Prooving stuffs like Cp-Cv=R using partial derivatives...
Sometimes they don't simpy give u R by leave it in the form of derivatives...
I can't reach iupto that
refer to page 33 of the pdf
Last part... Where the functions are expressed in differentials...
I can understand nothing over there.
 
You mean something like this?
8
Q: Relation between constant-pressure and constant-volume heat capacities: Cp - Cv = nR

orthocresolFor an ideal gas, we have $$C_p - C_V = nR$$ where $C_p$ is heat capacity at constant pressure, $C_V$ is heat capacity at constant volume, $n$ is amount of substance, and $R=8.3144598(48)\ \mathrm{J\ mol^{-1}\ K^{-1}}$[source] is the molar gas constant. How can I prove this?

 
Absoutely
But I can't decipher the properties and how they will break
btw refer to page 33 of the pdf that I sent u
Pls
 
 
11 hours later…
7:40 PM
3
Q: Is there a real detection limit in NMR spectroscopy?

orthocresolFrom what I've read, my impression is that with a sufficient number of scans etc., one can get spectra from even very dilute samples (S:N ratio ~ $\sqrt{\text{NS}}$). Obviously, this is not always possible in practice and it is not necessarily efficient use of instrument time. However, assuming ...

 
 
2 hours later…
9:46 PM
Hi all
 

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