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01:35
@pH13-YetanotherPhilipp okay
 
1 hour later…
02:51
@M.A.R.ಠ_ಠ You said you were gonna keep a "consistent name" ... ?
03:02
any chemdraw superuser? please have a look here
13 hours ago, by Gaurang Tandon
@[any-chemdraw-superuser] how much time would it take you to do this chemdraw conversion? (link) I spent exactly 20mins doing this, and am really looking to improve my efficiency, because if I continue at this rate I am in real trouble
many thanks
03:26
why didn't this get automatically deleted by the community user after 30days?
it was closed within five hours; should've been deleted within the next month; any idea why it's still alive?
@GaurangTandon views?
03:57
@AvnishKabaj nope, turns out that questions closed as "duplicate" are not deleted instead chemistry.stackexchange.com/help/roomba
why would Roomba want to retain them? no clue :/
 
5 hours later…
08:59
0
Q: What exactly is supposed to be the usage of [elements]?

Gaurang Tandonelements has 208 questions, of which 41 are currently closed (a whopping 20%!). The tag was created on Oct 2'14, and has no tag usage as of yet. This has resulted in a varied application of the tag. Of the 167 open questions, many could use alternate and well-defined tags: this could use rare-...

09:12
@AvnishKabaj Can you please delete those comments on that meta post?
they're distracting
for future visitors
many thanks
nvm you already did
 
4 hours later…
13:32
ACS reveals mercury was once a fashionable toy back in the 1950s
 
3 hours later…
16:52
another one with votes to close that is worth answering: chemistry.stackexchange.com/q/8667/194
3
Q: How are polarizabilities measured experimentally?

pentavalentcarbonMost common spectroscopies that produce either a full spectrum, a tensor, or a scalar value have a specific instrument associated with them that is relatively self-contained and not custom. For example, (linear) IR spectra come from benchtop FT-IR spectrometers, NMR chemical shifts use a FT-NMR s...

17:19
unfortunately i'm just an 8th grader without this theoretical experience. Hope you get a good answer @pentavalentcarbon
17:37
@Apoorv The \pu{...} construct can do more than just save you the typing of \mathrm{...}. It already sets the correct spaces and a multiplication sign with *: \approx \pu{4186 J/(K * kg)} is correct and much easier than \approx 4186~\pu{J/(K \cdot kg)}. — Martin - マーチン ♦ Feb 20 at 7:44
Actually the spaces of \pu are not correct.
@BountyHunter @penta -- Is the polarizability tensor symmetric?
Consider a poly-yne oriented along z
Maybe capped on one end with a hydroxyl or something
@hBy2Py Yes. Think about it: a non symmetric tensor is non-physical. Should the polarizability be dependent on which order the field is applied?
Sorry, I’m on my phone...
Ooooh, right.
Keep going
It's the 2nd spatial derivative of energy w.r.t. field
Yeah, nm
17:42
I have a big section about this in my dissertation
I better be correct
No, I retract my uncertainty
Units without uncertainty are unphysical too
I always thought that you could only measure a mean polarizability for most real stuff
Exceptions being highly ordered single crystal solids
That is also true
That goes for all spectroscopes, really
<nod>
17:47
But I don’t know how these experiments work
I assume it’s like EPR where you can get principal components for the equivalent of a powder, but I don’t know what the setup would be
Or how you would do “single crystal” polarizability
@pentavalentcarbon Anisotropy of the refractive index, I guess..?
@hBy2Py right. Is that a thing? Because I have no clue
Optics in materials gets crazy. Case in point:
Birefringence is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are said to be birefringent (or birefractive). The birefringence is often quantified as the maximum difference between refractive indices exhibited by the material. Crystals with non-cubic crystal structures are often birefringent, as are plastics under mechanical stress. Birefringence is responsible for the phenomenon of double refraction whereby a ray of light, when incident upon a birefringent material, is split...

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