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From the ideal gas (eqn of state) $$V=\frac{NK_BT}{P}\tag{1}$$
Where $P$ is the absolute pressure of the gas, $N$ is the number of molecules in the given volume $V$, $K_B$ is the Boltzmann constant, and $T$ is the absolute (thermodynamic) temperature.
The general equation for the internal energ...user116211
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The isoaspartate group is a functional group in biochemistry. Its formation is a chemical reaction in which the side chain of an asparagine or aspartic acid residue attacks the following peptide group (in black at top right of Figure 1), forming a symmetric succinimide intermediate (in red). The symmetry of the intermediate results in two products of its hydrolysis, either aspartate (in black at left) or in iso(Asp), which is a β-amino acid (in green at bottom right). The reaction also results in the deamidation of the asparagine residue.
== Kinetics of isoaspartyl formation ==
Isoasparty...
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Is bond formation "strictly" exothermic? The IUPAC definition of exothermic doesn't make any reference to bond formation. However, I have seen the aforementioned statement before - that bond formation is "strictly" exothermic.
I suspect that the answer is "it depends" and that "it depends" at l...user116211
An acyl group (/ˈæsɪl/ or /ˈeɪsaɪl/) is a functional group derived by the removal of one or more hydroxyl groups from an oxoacid, including inorganic acids. It contains a double bonded oxygen atom and an alkyl group.
In organic chemistry, the acyl group (IUPAC name: alkanoyl) is usually derived from a carboxylic acid. Therefore, it has the formula RCO–, where R represents an alkyl group that is linked to the carbon atom of the group by a single bond. Although the term is almost always applied to organic compounds, acyl groups can in principle be derived from other types of acids such as sulfonic...
Oxalyl chloride is a chemical compound with the formula (COCl)2. This colourless, sharp-smelling liquid, the diacid chloride of oxalic acid, is a useful reagent in organic synthesis. It can be prepared by treating oxalic acid with phosphorus pentachloride.
== Reactions ==
Oxalyl chloride reacts with water giving off gaseous products only: hydrogen chloride (HCl), carbon dioxide (CO
2), and carbon monoxide (CO).
(COCl)2 + H
2O → 2 HCl + CO
2 + CO
In this, it is quite different from other acyl chlorides which hydrolyze with formation of hydrogen chloride and the original carboxylic acid.
...
I need to get a high concentration of Genus Bacillus. Can I do this at home?
First of all, you have it all backwards.
You sound like the $\ce{AlCl3}$ says, "Oh, I am in solid state now! Let me turn to crystal (polymer) structure! [a while later] Oh, I am in vapour state now! Let me turn to dimer structure!"
Where in reality it says, "I don't have enough kinetic energy t...
I'm translating a where antibody deamidation is mentioned.
One sentence goes like this:
We used reversed-phase HPLC to analyze the aspartyl forms of the monoclonal antibody. (Russian original text: "изоаспартильные формы")
However, in scientific papers the word is "isoaspartate", not "isoa...
Transcript for
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Sep '1620
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The Periodic Table
Haikus are awesome / Chemistry's even better / So pull up a chair
