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03:31
What is the difference between the two non-bonding orbitals of cyclobutadiene?
!!img/cyclobutadiene
!!img/C1(H)=C(H)C(H)=C1(H)
I am referring to the molecular orbitals formed by the atomic p-orbitals
 
3 hours later…
06:53
0
Q: So many atomic radii

Varun ChandraWhy are there so many different atomic radii of only one element on the internet ? Even if i search for covalent radius every site shows different values . I want all the trends and exceptions of atomic radii but i can not find the correct site to get the values on which I can rely. Even my book ...

... the title though...
If I react propene with KMnO4, I will get 1,2-propandiol?
* propane-1,2-diol
I don't understand why this reaction takes place
07:25
Yes, according to this answer sheet, I was right. But why do we get KOH in the final reaction..
This page says KMnO4 can disrupt C-C bonds in a glycol. So the reaction may proceed further and tear the 1,2-propandiol apart?
 
2 hours later…
09:33
Hello~~Does anyone here have experience with polycrystalline materials? Either ab initio or experimental?
user116211
10:21
in The h Bar, 2 mins ago, by MAFIA36790
Worldbuilding graduated!!
user116211
in The h Bar, 2 mins ago, by MAFIA36790
The best site-design ever I got to see ;)
10:42
@CowperKettle
Nucleophilic attack?
 
5 hours later…
15:40
@hippa Did you hire xkcd to post a funny story every day on Chemobot ? (Or does it do it by himself.)
@Ramanewbie Magic
NO MORE MAGIC
@hippa Alright, you created this account to post a comic everyday didn't you
?? What with it ?
Yes I saw that already.
For ages I thought he was sb though.
16:44
!!help
Hi! I'm the almighty bot of ChemistrySE's main chatroom. /!\ If you find me annoying, you can ignore me by clicking on my profile image and chosing "ignore this user" /!\ You can find my documentation here.
!!greet/@Chemobot
Welcome to The Periodic Table @Chemobot! Here are our chat guidelines and it's recommended that you read them. If you want to turn Mathjax on, follow the instructions in this answer. Happy chatting!
$\ce{}$
$\ce{N}$
$\mathrm{CH_3OH+BF_3\to CH_4+BOF_3}$
is this correct?
!!img/BOF3
<An error occured : cannot identify image file '3229//temp//mol.gif'. Check your molecule's name.>
16:53
!!img/ch4
<An error occured : cannot identify image file '3229//temp//mol.gif'. Check your molecule's name.>
!!img/ch_4
<An error occured : cannot identify image file '3229//temp//mol.gif'. Check your molecule's name.>
!!img/boron-oxy-flouride
<An error occured : cannot identify image file '3229//temp//mol.gif'. Check your molecule's name.>
16:57
does $\mathrm{BOF_3}$ exist?
17:20
@DeNiSkA search by chemical name not formula
!!img/methane
<An error occured : cannot identify image file '3229//temp//mol.gif'. Check your molecule's name.>
or not lol
haha
i've only ever seen it searched by name though, and I know that works... usually
!!wiki/hello
17:22
Hello is a salutation or greeting in the English language. It is first attested in writing from 1833. == First use == Hello, with that spelling, was used in publications as early as 1833. These include an 1833 American book called The Sketches and Eccentricities of Col. David Crockett, of West Tennessee, which was reprinted that same year in The London Literary Gazette. The word was extensively used in literature by the 1860s. == Etymology == According to the Oxford English Dictionary, hello is an alteration of hallo, hollo, which came from Old High German "halâ, holâ, emphatic imperati...
!!img/methanol
<An error occured : cannot identify image file '3229//temp//mol.gif'. Check your molecule's name.>
!!greet/@Benzene
Welcome to The Periodic Table @Benzene! Here are our chat guidelines and it's recommended that you read them. If you want to turn Mathjax on, follow the instructions in this answer. Happy chatting!
Whats up with the image function @Loong?
Any idea?
17:24
You broke it?
Don't tell anyone!!!!!!!!!
hein! he broke it? how?
!!test
edited !
17:28
@Benzene hi
@Benzene I saw in your bio that you're going to UT Austin next year
yeah
I'm actually attending right now
cool
how are you liking it?
17:30
Very nice
I only wish there wasn't so much construction
@ringo isn't Todd Minehardt in Austin, too?
Yeah, he taught there for a while
I think he went there too
what year are you?
I'm going to be a third year next year
17:36
cool
@Benzene ._. that black background is weird
@Hippalectryon What happened to Chemobot's images?
It is the image that I use for everything
@Loong It didn't change ?
!!coffee
17:42
!!img/4-(acetyloxy)benzoic acid
<An error occured : cannot identify image file '3229//temp//mol.gif'. Check your molecule's name.>
@Hippalectryon ^
@Benzene I'm nt saying it's bad :P
lol, kk
17:43
-1
Q: What happens when H+ ions react with OH- ions?

Abdul Moiz QureshiSome of the properties of such an ionic compound that I have already predicted are: . It will be a salt. . It will have a high melting and boiling point. . It will be an isomer of water [H2O]. In addition to the above, please give additional properties of this hypothetical substance, make correc...

.................
@orthocresol Wow. A new salt has been invented, and we downvote the inventor.
Such is the fate of all great inventors.
I'll go boil meself a cup of salt for some coffee
@or
*@orthocresol, should I post an answer for my antiaromaticity question?
18:39
@Benzene what question?
oh nvm, I found it
ah.. It's up to you. Self-answers are good things on SE!
I haven't had much time lately to answer stuff... and won't have much time in the next few weeks because exams...
19:00
Notice : chemobot now returns for the img command the first result it finds on chemspider. So don't be surprised that command works !!img/acid lol
(Chemspider auto corrects it to acidol)
user116211
19:14
@hippa o//
user116211
!!greet/@Benzene
Welcome to The Periodic Table @Benzene! Here are our chat guidelines and it's recommended that you read them. If you want to turn Mathjax on, follow the instructions in this answer. Happy chatting!
@orthocresol: thanks, I will
Hi
user116211
Okay, Henderson-Hasselbalch equation is giving me a shit ;(
19:15
?
user116211
Why it is an approximate ;_;
user116211
As Peter Atkins writes:
By this logic, it should be exact:
In chemistry, the Henderson–Hasselbalch equation describes the derivation of pH as a measure of acidity (using pKa, the negative log of the acid dissociation constant) in biological and chemical systems. The equation is also useful for estimating the pH of a buffer solution and finding the equilibrium pH in acid-base reactions (it is widely used to calculate the isoelectric point of proteins). The equation is given by: Here, [HA] is the molar concentration of the undissociated weak acid, [A⁻] is the molar concentration (molarity, M) of this acid's conjugate base and pKa is −log10 Ka where Ka is...
user116211
wait
user116211
I'm not Barry Allen
user116211
19:20
> $$\mathrm K_a= \frac{a_{\ce{H_3O^+}} a_{\ce{CH_3CO_2^{-}}}}{a_{\ce{CH_2COOH}}}\approx \frac{a_{\ce{H_3O^+}}[\textrm{base}]}{[\textrm{acid}]}$$
user116211
Why did he use the approx. sign viz $\approx\;?$
user116211
I'm not getting that.
user116211
@hippa did you add new features to Mr.Bot?
@MAFIA36790 I don't think so. But I can if you want. I just changed the way it fetches images
user116211
@Hippalectryon ohh... I wished earlier for xkcd.... if you think....
user116211
19:25
BTW, your oral exams are over?
@MAFIA36790 $\mathrm pK_\mathrm a + \log\dfrac{[\mathrm A^-]_0}{[\mathrm{HA}]_0} \approx \mathrm pK_\mathrm a + \log\dfrac{[\mathrm A^-]}{[\mathrm{HA}]} = \mathrm{pH}$
one fraction refers to initial concentrations; the other fraction refers to actual concentrations in equilibrium
@MAFIA36790 Not even started lol
@MAFIA36790 Ok I'll do that
user116211
@Loong processing; nevertheless thanks.
user116211
!!greet/@roscoe_casita
Welcome to The Periodic Table @roscoe_casita! Here are our chat guidelines and it's recommended that you read them. If you want to turn Mathjax on, follow the instructions in this answer. Happy chatting!
user116211
19:35
> Suppose we add enough titrant to produce a concentration $[\textrm{base}]$ of the conjugate base and simultaneously reduce the concentration of acid to $[\textrm{acid}]$. ....
user116211
@Loong: Is he talking about the initial concentrations?
I suppose so
user116211
@Loong ohh...
user116211
OHHHH!!!!!
user116211
I think I GOT it!!!
user116211
19:38
Lemme explain...
user116211
2 min
user116211
He writes $\textrm K_a$ for this $$\ce{CH_3COOH + H_2O <=> H_3O^+ + CH_3CO_2^-}\;.$$
user116211
But actually he uses the concentration for computing $\textrm K_a$ he got from this $$\ce{CH_3COOH + OH^- <=> H_2O + CH_3CO_2^-}$$
user116211
@Loong: Tell me this is not insane or is it?
user116211
I think that's why there was the approximation sign and not the equality one.
user116211
19:46
::Sigh::
@MAFIA36790 I guess, these are the formal concentrations of the acid and base; but since you use a weak acid and a weak base for a buffer, the actual concentrations in equilibrium could be different.
user116211
ohh...
user116211
Whatever it is, the equation is approximate; that's for sure; isn't it @Loong?
user116211
@Loong yeh, that...
user116211
19:57
Meanwhile, got this:
user116211
I've to read a bit more between the lines to get hold of this.
user116211
Bye @Loong and all my comrades; good night ;))
cu
20:10
@MAFIA36790 try it :-) xkcd/...
what are the arguments?
@Benzene The id of the comic strip
!!xkcd/1
nice!
20:30
here is a stupid question.... do 'ions' exist? or are they purely a modeling tool?
@roscoe_casita sure they exist
did you read about how that French scientist first discovered that they exist, on salty bank of a lake in Egypt?
hrmmm, I'm a horrible newbie when it comes to chemistry
neg
Me too.
link / info?
Oh, I forgot the precise link. The scientist is famous, but I'll drop asleep now, and I forgot his name
20:36
noooo!
Claude Louis Berthollet (9 December 1748 Talloires, France – 6 November 1822 Arcueil, France) was a Savoyard-French chemist who became vice president of the French Senate in 1804. He is known for his scientific contributions to theory of chemical equilibria via the mechanism of reverse chemical reactions, and for his contribution to modern chemical nomenclature. On a practical basis, Berthollet was the first to demonstrate the bleaching action of chlorine gas, and was first to develop a solution of sodium hypochlorite as a modern bleaching agent. == Biography == Claude Louis Berthollet was born...
This seems to be him
thanks =)
you're welcome (0:
Berthollet and Soda lakes
He discovered that the reaction went in reverse to the reaction in a lab

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