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Q: Grasping the concept of Electronic Spin (S), Effective Spin ($\widetilde{S}$) and Fictitious Spin (${S}'$)

Henrique JuniorTrying to learn alone some aspects of quantum mechanics is, sometimes, a struggle. Reading the excellent paper by Piwowarska (DOI 10.1007/s00723-018-1080-4) I was hoping to, finally, understand what is the origin of the so-called “fictitious spin ½” in a d7 cobalt ion. If my cobalt is high spin ...

quantum-chemistry computational-chemistry electrons spin epr-spectroscopy

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