I got a little confused at first what to use for images, because there were many different tutorials.
Some told you to use epsfig
or something. It took me a while to figure that some packages are simply outdated.
Also at the beginning I tried to use as few packages as possible, because I thought they slow down in compiling much, but I stopped doing that very quickly.
Some other things like \raggedbottom etc. were a little funny at the beginning as well, but I got used to it.
In summary, I liked LaTeX a lot better than Word after a short while, but had the impression that it was a little strict, which has its drawbacks if you want to write a thesis, where the professor has a certain layout in mind.
I got here first because I was looking for some LaTeX macro or solution (can't remember what exactly). I knew stackexchange a little before and was surprised in a nice way to find a TeX version of it.
I liked the Q&A format and the fact that there is no much noise here, like in forums.