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user116211
2:51 AM
Seriously one of the worst days of my life.
 
user116211
All the trees that I was seeing right from my childhood days are now being cut just for making some petty construction.
 
user116211
Literally tears came down ;_;
 
user116211
Many moments of my life were connected with those trees T__T
 
user116211
How could they be so barbarian just ending with few minutes the beauty of the creation?
 
user116211
They were right in front of my study-table window; I would cherish the pleasant breeze during the evenings and those aroma of the flowers at the dead of the night; they were always with me when i was studying late at night.
 
user116211
2:56 AM
How could I, a single person, stop this ;( I feel never so powerless in my life.
 
user116211
They could have spared those trees as they were just at the corners of the boundary; but what could you do when greediness infects one with dumbness and stupidity ;/
 
user116211
No one protested; dumb idiots ;((
 
user116211
I'm devastated today.
 
user116211
@Jan Sorry, couldn't post the result as my internet plan got expired.
 
user116211
@Loong I knew they would make it.
 
user116211
2:59 AM
Germans are the best.
 
user116211
Well, okay, I'm not in mood today ;(
 
user116211
@Jan: I know it would be racist but well, most of the stupid answers come from Indians ;/ They think they have known everything and could answer anything; when they can't or feel uneasiness, they apply circular logic.
 
user116211
Hmm, I'm speechless today; I'm really depressed; I'm unable to concentrate on my studies.....
 
9:51 AM
@zʏᴀʙiɴ101 me :D
oops wrong chatroom ._.
 
10:07 AM
@Chemobot I feel like kicking you now.
 
10:20 AM
nooo
 
 
5 hours later…
3:31 PM
How does one call the mass of a marker calculated from its chromatography plot?
A "calculated mass"?
 
@CowperKettle "mass".
Why should we be specific?
 
?
> If the difference between the calculated and actual molecular mass for one of the markers exceeds ±10%, a fresh solution of this marker is prepared, then chromatographed twice, after which the average retention time for the marker is calculated and a new calibration curve is plotted.
I know very little about chromatography, so this may be a very awkward translation from Russian.
 
There's no technical word for this that I know. Just say "the mass, as the chromatography analyses indicate, is <some badass numbers>"
@CowperKettle You verbified "chromatography". DUDE
DUUUUUUDE
 
I googled, and it's okay
 
Actually, I love your translation, except for the verbification part.
 
3:37 PM
"subjected to chromatography" is a bit off
 
@CowperKettle But not sciency.
 
I tried to compress it
I did not know we can calculate the molecular mass by measuring chromatographic peaks
 
@CowperKettle Eh, analytical chem is all about getting people's phone numbers from a bunch of irrelevant lines.
You can never know how powerful human interpretation of physical phenomenon can be.
 
Jan
4:38 PM
@Chemobot Chemobot can talk? O___O
@TIPS I chromatographied all my substances …
@MAFIA36790 There is a lot of unintended the Indians — I’m guilty of it, too =C
 
5:06 PM
@Jan including the precious bodily fluids?
^_^
Good evening!
 
 
2 hours later…
6:43 PM
2
Q: How to explain Born repulsion between ions in gas phase?

Linear ChristmasIn simple terms, the collision of two atoms $\ce{A}$ and $\ce{B}$ will result in ions $\ce{A^+}$ and $\ce{B^-}$ if $$I_a(\ce{A})+E_a(\ce{A})<I_a(\ce{B})+E_a(\ce{B})$$ where $I_a$ and $E_a$ are the ionisation energies and electron affinities, respectively. Let us view $\ce{A^+B^-}$ as a molecule o...

 
 
1 hour later…
8:06 PM
Is anyone around?
 
 
2 hours later…
Jan
9:55 PM
!!img/formazanate
 
No result found.
 
Jan
Oh boy .__.
!!img/formazane
 
Jan
Ah, now that's helpful. Thanks @Chemobot
!!img/CHeMoBOTe
 
No result found.
 
Jan
10:01 PM
What a shame =C
 
 
1 hour later…
Jan
11:04 PM
Oh … Why am I no longer porphyrin in chat?
 
@Jan you are for me
 
Jan
Hm. Reloaded and I am again.
Apparantly, my chat profile was linked to chemistry all along but changed back to German once I hit … actually no that doesn’t make even the slightest of sense. I have an avatar on German.
 
11:18 PM
You can have different profile pictures?
 
11:29 PM
@pentavalentcarbon of course
 
@TIPS Is that related to how when I modify my profile I get asked if I want to propagate the changes to all the Stack Exchange sites I'm on?
 
@Jan heh, you want a bug to make sense?
@pentavalentcarbon Precisely
You can also have different about me's.
 
Jan
@TIPS Which is also precisely what I have (CC @Pen)
 
Hmm, I'm boring, I don't really participate in other SEs, and barely this one...
 
Jan
@TIPS Actually, some bugs do make sense, if you figure out things like 'oh yeah, it just takes the user's top rep site and changes that every now and again'. But then I realised that my sense making wasn't making sense.
You can't be boring, you're @pentavalent! And a carbon! That's some interesting chemistry! ;)
 
11:35 PM
@Jan Don't sense make sense make sense then.
 
@Jan I think carbon is very boring, and chemistry is kind of boring too...
 
@pentavalentcarbon so is the rest of the universe, really.
You're not missing out much.
 
all my organic friends think there's only something like 7 elements...
as opposed to the non-organic lifeforms I know
 
Jan
@pentavalentcarbon 7? That many?
 
Jan
11:38 PM
I mean, there's carbon and hydrogen and oxygen and nitrogen and chlorine … and … sodium exists in mass spectrometers and …
 
@Jan You aren't doing your people any favors right now, but I'll forgive you since your porphyrin is coordinated, though only half-points because it's closed-shell.
 
@Jan And krypton . . . ite.
 
Jan
I love doing my kind non-favours ;)
 
My friends mostly work for a boron lab. One uses rhodium or ruthenium, another tin.
 
Jan
Now being a little more serious, which elements did I actually use in my total synthesis to date?
 
11:46 PM
 
Realistically, I'd guess not many. I find it pretty interesting how most of the elements only see one or two applications each, but they're very important in that role.
 
Jan
H, Li, B, C, N, O, F, Na, Al, Si, P, S, Cl, Ar, K, Ca, Ti, Mn, Fe, Cu, Br, Ru, Pd, Ag, Sn, I, Ce, Yb.
I've also already used Os in a different synthesis™.
 
@Jan Interesting idea. I should read my thesis again and count the elements. :-)
 
Jan
@Loong Please do so, but please add a count for every radioactive isotope xD
 
ok
 
11:56 PM
Ce and Yb? That's pretty interesting, I only know about them in ceramic superconductors.
 
Jan
Yb(OTf)3 is a Lewis acid required for Gooßen’s amide-alkyne addition and Ce is part of the 'yellow sperm' staining solution xD
Meaning I forgot Mo. Oh well.
 

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