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1:56 AM
hello
 
2:22 AM
Hi
 
when we left off yesterday, was 0 incorrect?
 
2:38 AM
I have what may be a very silly question about the scientific community's conception of the burden of proof and falsifiability....
 
@Wildcard, ask away =)
 
I understand in general that a theory, to be considered a scientific theory, must be possible to falsify; i.e. there must be a possibility of information existing which could in itself indicate that a theory is false.
But, that hardly seems sufficient to call a theory "scientific"—and how could a theory be proved, ultimately, other than heuristically?
For instance: "Nothing can go faster than the speed of light."
I suppose this is falsifiable, because if I were to go faster than the speed of light it would be shown to be false.
 
well, you could also say that if theories are inconsistent, one must be false.
 
But, if I were to say something stupid such as, "No person can have six legs," it is falsifiable for the same reason—and yet the absence of a readily visible person with six legs hardly indicates that this is scientific.
@heather That's fair. I was still writing out my thoughts. ;)
I'm a little unclear how falsifiability relates to the burden of proof.
It seems that the best one can achieve is to make an internally self-consistent theory....
But then how does that fit with "burden of proof"?
For instance, "There is a Creator," is "not a scientific theory" because you cannot demonstrate that there is not a Creator, so it's not falsifiable.
 
well, I'm honestly not the best person to answer these questions. however, i would point out that whenever physics has been thought to be solidly established (aristotelian physics, newtonian physics, etc) it has been swept away or refuted by new discoveries.
 
2:44 AM
@heather I guess that's where I'm really going with this.
 
also, in terms of a Creator, by that same argument the multiverse/many worlds theory is not a scientific theory, yet it is treated as one.
 
I suppose it has a lot to do with the relationship of science to philosophy.
@heather Perfect example. String Theory is an even worse example of the same thing.
 
Mew
@heather many worlds theory isn't thought of as a scientific theory though by most physicists
 
I could sidestep the whole thing by concluding, "People will believe what they want to believe, including scientists, and they will invent yardsticks for the validity of theories which will assert that they are right."
But that's not really helpful either (even if true.)
 
Mew
the interpretation of QM is considered to be outside of physics scope currently as no experiment can distinguish between them
it is more philosophy
only physics when experiments are proposed to differentiate them
 
Mew
@Wildcard no theory can be proven true
@Wildcard the goal of string theorists is to come up with a prediction that can be tested
but until they do so, string theory isn't a mainstream scientific theory
 
and now we say darn philosophy and keep studying physics =)
 
@Mew Okay, I suspected as much. (Or rather, that's what I had concluded, and am attempting to reconcile with the idea of a "burden of proof.")
 
Mew
@Wildcard science doesn't have a burden of proof
 
but there is a sort of line between scientific theory and non-scientific though admittedly it is hard to define (for me at least).
 
Mew
2:49 AM
@heather yes, a scientific theory must be falsifiable
at least in principle
and it must be consistent with observations to date
and we usually use ocaam's razor as a guiding principle
 
@Mew But ultimately, it can never be proven true with the sort of conclusiveness that is achieved in mathematics. Correct?
(Because in mathematics, things are true by definition.)
 
Mew
@Wildcard correcvt
it is about getting the best approximation of reality we can
our theories are never 100% true
they are always evolving over time
from Newton to Einstein to Schrodinger
better approximations over time
 
@Mew, but many-worlds theories or string theory...
 
Mew
and I"m sure this trend will continue
 
@Mew And the idea of sampling bias, and so forth, but those are questionable theoretical ideas (compared to the scientific method itself).
@Mew This makes sense to me.
 
Mew
2:52 AM
@heather most physicists agree many wolrds is an "interpretation" not a scientific theory
 
and string theory?
 
Mew
most physicists are also sskeptical of string theory
because at present there are no experiments to verify it
 
true
 
Mew
but a physicist can still work on it if they believe eventually they can come up with a falsifiablle prediction
 
thanks for the conversation, very interesting
i have to go now =)
so good night everyone.
 
Mew
2:53 AM
but if it turns out there can never be a falsifiable prediction, string theory will be buried for sure
 
@heather Okay, thanks! :)
 
@Wildcard, not a problem, glad you asked =)
always feel free to just ask, no need to ask to ask.
 
@Mew Buried as a scientific idea, perhaps, but it sure doesn't mean people won't still believe it.
 
Mew
@Wildcard but by occams razor why would you believe in it?
most rational people won't believe in something where there is no reason to do so
why believe say invisible fairies pushing planets around causes gravity when there is no reason to do so
 
@Mew Ask Richard Dawkins.
@Mew If you take a personal dislike of religion as a reason, then he certainly has a reason. :)
 
Mew
2:55 AM
people will always believe different things, but that isn't relevant for determing what is a good scientific theory
 
@Mew I agree with you. The most important trait for a good researcher, in my opinion, is the ability to see past one's own personal prejudices. And to change them.
 
Mew
Personal beliefs don't even need to come into play when doing research
A belief in god doesn't mean you can't do good work in QM
 
@Mew When one is researching, one is using one's mind.
 
Mew
I think a good scientist can separate beliefs from observations and reasoning
everyone has beliefs of some kinds, they are essential for getting by in life
 
All other aspects of research are secondary to the ability to use one's mind well. Notes, equipment, case studies....
@Mew Agreed.
 
Mew
2:59 AM
but as you said a good scientist won't include these beliefs in their work, only observations and reasoning
 
user116211
@JohnRennie An explicit point-wise explanation on JD's stand for the first-time; hope he reads that. I was expecting such post to come there; that was somewhat fulfilled by Gennaro, but this is a neat record on his deeds here. Although I'm sure, it wouldn't change his opinion, but I'm eager to see his response, if any; +1.
 
@Mew And predictions. Don't forget that.
Beliefs can play a VERY important role.
 
user116211
@AccidentalFourierTransform Just enjoying learning new things!
 
user116211
@DanielSank o/
 
Successfully challenging a widespread assumption of the impossibility of a certain task is, I would contend, NEVER otherwise than the result of one's personal belief that the task is possible.
If we ever do exceed the speed of light, you can bet it won't be conceived of and implemented by someone who believes it's impossible to go faster than the speed of light.
Most major scientific breakthroughs (not mere feats of engineering in applying existing knowledge, but NEW discoveries) were widely considered as impossible before they were accomplished.
More succinctly: Evidence is only found through observation.
@Mew Actually, I think "reasoning" has very little to do with scientific accuracy. Reasoning can ALWAYS be overturned by observation. "It still moves."
 
3:42 AM
Current chat occupancy
$$\lvert \textrm{Me}\rangle = \frac{1}{N}(\lvert \hbar \rangle + \lvert \textrm{maths}\rangle+\lvert \textrm{Mos Eisley}\rangle)$$
 
user116211
@Secret Why did you go to Mos?
 
Recently I have a harry potter question
 
user116211
Rogue One?
 
user116211
@Secret oh
 
nope, I plan to watch Rogue one on thursday
 
user116211
3:44 AM
okay
 
In other news, when trying to formulate a way to organise Light's associativity test, G. Bergeron found I might have used the set builder notation wrongly, and Tobias Kildetoft does not quite understood what I am trying to do.

I am not sure what goes wrong, but it might be I have used the cartesian product in a wrong way when defining a set that depends on elements in such set

(details to be reposted in seconds)
2 days ago, by Secret
Def. 1. All elements in a Cayley table

Given a magma $(M,\circ)$, Let $S=\{s_1,s_2,\dots,s_n\}$ be the ordered set obtained by imposing an order $\mathcal{O}$ onto M. Then the cayley table $T$ is given by $T=\{\ x\lvert \forall (a,b) \in S \times S, a\circ b=x\}$. The tranpose is defined by $T^\textrm{T}=\{\ x\lvert \forall (b,a) \in S \times S, a\circ b=x\}$.


Def 2. Rows and columns and collections

A row $R_i \subset T$ is given by $R_i= \{\ x\lvert \exists i \in S,\forall (a,i) \in S \times S, a\circ i=x\}$. Similarly, a column $C_i=\{ x\lvert \exists i \in S,\forall (i,b) \in S \time
The whole thing in plain english: I have a magma. Def 1
tries to impose an ordering to the underlying set of the magma (which has n elements , thus the magma has $n^2$ elements in total including the products)
T thus gives the cayley table under $\circ$
which can be transposed by swapping the ordered pair around
Def. 2, fixes one of the entries of that ordered pair so that you get rows and columns of a cayley table instead. Def. 3 uses multiplication by elements in a magma elementwise to the rows and columns so it maps rows to rows and columns to columns
Theorem 1 than give the criteria for the magma to be associative is that when rows can always be map to rows without leaving the set of all rows of the cayley table
and Lemma 2 showed that proving all rows are closed under the magma action is sufficient to show associativity because rows and column operations are related by the transpose
 
3:59 AM
@MAFIA36790 \o
 
user228700
@JohnRennie: And this has been sitting here, all along... (::facepalm::)
 
user228700
7
Q: Justification for Freezing Point Depression & Boiling Point Elevation in Solutions?

Tyreke DavisI was wondering if the following justification for freezing point depression and boiling point elevation are conceptually correct. The reason why I ask this question is because I have been self studying chemistry for a course I will be taking this fall, and I don't have a human reference to check...

 
user116211
So, you are all in a voyage to show the magma is a semigroup @secret?
 
yeah, and if the above can be formulated rigorously and (more importantly) understandable to those in the field, then it is potentially powerful because you can actually check by looking at the cayley table whether the structure is associative, and where exactly will the associativity will break if it is not a semigroup
that is, the above attempt will end up putting the two tables of light's associativity test on top of each other, thus if the row and columns in the cayley table are closed under that "magma" action, then the magma is associative and hence a semigroup
 
0
Q: Hypergeometric Function: Differential Equation

user139383In Birrel Davies: QFT in curved spacetime it is written that the following differential equation can be solved in terms of hypergeometric functions. $$(\partial_t^2 +(k^2+c(t)m^2))\phi(t)=0$$ But there is no reference and no method listen. Could somebody please help me solve this equation for $c(...

send to Mathematics?
 
4:11 AM
@DavidZ right now it is too maths oriented. Either suggest the user to put more physical context to the question or sent it to maths
 
Mew
@Wildcard yes reasoning isn't good for determing accuracy but it's good for coming up with theories to then test experimentally
@Wildcard e.g. Einstein's special relativity was derived through reasoning but thne tested with observation. Of course like you say, if observation didn't reconcile with the theory the theory would need to be discarded despite reasoning being in its favour
@Kaumudi.H how is the new laptop?
 
user116211
@DavidZ I would say it's not fit for here; but would wait for the community.
 
user116211
In anyway, it looks like homework.
 
@MAFIA36790 you are the community :-P
 
user116211
I'm a part of the community.
 
user228700
4:37 AM
@Mew It's excellent and still waiting at Customs (-_____-)
 
user228700
@JohnRennie: Morning, morning! :-) I've a quick question. The definition of the freezing point of a liquid is given as:
 
user228700
> "The temperature at which the vapour pressure of the solid becomes equal to the vapor pressure of the liquid"
 
user228700
Why is this the definition?
 
user116211
4:53 AM
@Kaumudi.H And why do you feel it should be otherwise?
 
user228700
Uhh, I don't. I'm unable to understand why this definition makes sense.
 
user228700
@Mew: I've just learned about osmosis and have figured out why my two fish died, all those years ago. I was a kid, how was I s'posed to know?! :-(
 
5:27 AM
In computing, row-major order and column-major order describe methods for arranging multidimensional arrays in linear storage such as random access memory. In row-major order, consecutive elements of the rows of the array are contiguous in memory; in column-major order, consecutive elements of the columns are contiguous. Array layout is critical for correctly passing arrays between programs written in different languages. It is also important for performance when traversing an array because accessing array elements that are contiguous in memory is usually faster than accessing elements which are...
I found it very hard to phrase my ideas in precise mathematical language because I often think in terms of arrays, and trying to find set builder notations that can give me the ordering of arrays
 
user228700
5:39 AM
If anybody in interested in the following article about demystifying osmosis, please give it a read and let me know if u agree with the writer's hypothesis:
 
5:50 AM
@Kaumudi.H It's true, but not a wonderfully useful definition.
The free energy of the molecules in the solid and the free energy of the molecules in the vapour above the solid are equal because they always are when there is equilibrium.
And likewise for the liquid: the free energy of the molecules in the liquid and the free energy of the molecules in the vapour above the liquid are also equal.
 
user228700
And since free energy is directly proportional to pressure, it makes sense to use this definition, yeah..?
 
So if the free energies of the vapour above the solid and the vapour above the liquid are equal that must mean the free energies of the molecules in the liquid and solid are equal.
@Kaumudi.H I wouldn't have said it's a very useful definition.
 
user228700
Alrighty. I've another quick question (which may lead to a bigger question, oops). Shall I go on..?
 
Yes, go ahead
 
user228700
Is it OK to think "Osmosis occurs due to a concentration gradient"? I've come across other explanations but haven't really understood any of them properly. Is it worth the time or should I just accept this and move along..?
 
6:02 AM
Well molecules bounce around randomly due to thermal motion.
And the number of molecules bouncing randomly past any point will be proportional to the concentration of molecules near that point.
 
user228700
Right, right, but look at what this person is suggesting:
 
user228700
> "Yes, the concentration of water is lower on the right side, but what does that mean to any individual pore? If a sugar molecule is not nearby the pore, the water concentration is the same on both sides of the pore, and if a sugar molecule is close enough to the pore to prevent water molecules from escaping right-to-left, it is also blocking water molecules from entering left-to-right. When a sugar molecule blocks a pore, it blocks water flow in both directions, indiscriminately."
 
user228700
 
I find it hard to raise much enthusiasm for that argument. The sugar molecules don't block pores
 
user228700
What about this:
 
user228700
6:06 AM
> "If a sugar molecule is not nearby the pore, the water concentration is the same on both sides of the pore"
 
@JohnRennie why are you taking to a cat?
 
The flow of water through the semipermeable membrane has nothing to do with sugar molecules blocking the pores in the membrane.
@DanielSank it's a NAND cat!!
 
user228700
@JohnRennie THANK YOU!! @DanielSank: x-(
 
user228700
@JohnRennie Right...
 
Lolol
 
user228700
6:09 AM
I too found it a little difficult to believe what the O.P is saying.
 
@Kaumudi.H that's also meaningless. Concentration is an average property and it's averaged over a large number of molecules. Osmosis is a net flow where we average the flow rates over a large number of molecules.
To talk about individual molecules is meaningless.
You've finally found a source even worse than your textbook :-)
 
user228700
Why, tho? Why is it entirely meaningless?
 
user228700
@JohnRennie The level of suck that my textbook contributes to this world is now a well-known fact hereabouts :-P Nothing can beat my textbook's expertise in this field.
 
is so tempted to star that
 
user228700
:-)
 
6:14 AM
In a sugar in water solution the molecules are all buzzing around randomly and there will be local variations in the densities of water and sugar molecules just due to random chance.
 
user228700
Riight...
 
user228700
(Sorry about that. My mum needed me)
 
user228700
Can u pls go on..? Why is the O.P's argument addressing individual particles meaningless..?
 
user228700
Hiya @Mew :-)
 
halo
osmosis is weird I too haven't been satisfied with the standard explanation
@Kaumudi.H my name isn't mew anymore btw
 
user228700
6:28 AM
Yeah :-| My question is whether it's worth it to understand it in terms of chemical potential and whatnot.
 
user228700
@Kenshin Um, it still says "Mew".
 
oh relaly
it doesn't on my computer
that's weird
 
user228700
Give it some time, maybe...
 
when you pinged me did you type @mew? or @kenshin?
because it says you typed @kenshin
 
user228700
Uh, I typed "Mew", man.
 
6:29 AM
@Kenshin Um, it still says "Mew".
^ that is what it says u typed on my computer
silly computers
 
user228700
 
user228700
Ah, it's changed just now @Kenshin :-)
 
cool
@Kaumudi.H the article you linked, that was my theory too on osmosis
 
user228700
Anyhoo, @JohnRennie: Shall I come back later or s'thing..?
 
that the non-permeable substance pushes the membrane out
 
6:32 AM
@Kaumudi.H sorry, work called for a moment.
 
but it even says on the website at the bottom that the theory can't explain all instances of osmosis
 
user228700
Ah, but JR says that it's meaningless to talk about individual molecules.
 
Where had we got to?
 
@Kaumudi.H why though? everything works ultimately on molecular level
 
user228700
@JohnRennie We were trying to figure out why talking about individual molecules is meaningless.
 
6:33 AM
@JohnRennie how does osmosis work?
why does water flow from high concentration of water to low concentration of water
when the pressure of water is already equal on both sides
where does the additional "osmotic" pressure come from?
what wizardry is this?
 
user228700
The pressure of water isn't equal on both sides tho. Why dyou think it is?
 
oh
 
@Kaumudi.H because the solvent flow in osmosis is a net flow i.e. the average over many molecules. You can't tell what's going to happen by looking at a single moecule or just a few molecules.
 
well let's ignore osmotic pressure for now
and consider hydrostatic pressure
is the hydrostatic pressure on both sides of th emembrane equal?
 
user228700
@JohnRennie Yeah, I guess that makes sense.
 
6:35 AM
well i guess osmotic+hydrostatic is equal on both sides right?
 
user228700
@Kenshin Presumably, yes. Well, after all of the osmosis has taken place, anyway.
 
yeah
let's just consider after osmosis for now
there are two forces at work
(1) hydrostatic pressures
and (2) osmotic pressures
I think the total of (1) and (2) on the left membrane equals the total of (1) and (2) on the right memebrane for both substances
do you agree @JohnRennie
 
user228700
Huh? Isn't osmotic pressure defined for the whole system?
 
like as a pressure difference?
I guess, I"m not sure how it's conventionally defined
I'm just thinking about the system
not necessarily the conventional definitions
but we can use whatever definitions you prefer
 
user228700
> "The pressure that would have to be applied to a pure solvent to prevent it from passing into a given solution by osmosis"
 
6:38 AM
If you let the system reach equilibrium then the hydrostatic pressure will be higher on one side of the membrane than the other. The pressure difference across the membrane is equal to the osmotic pressure.
 
@JohnRennie agreed
 
user228700
^ It doesn't look like there's a different osmotic pressure for each comportment and all...
 
user228700
@JohnRennie Ah...
 
@Kaumudi.H yeah it's up to you how you think about it, whether you treat it purely as a pressure gradient or a difference between compartments, I've seen texts use both treatments
 
user228700
Hang on tho, what are u saying? That without applying that external pressure the system won't be in equilibrium?
 
6:39 AM
in medicine you often allocate an osmotic pressure to both compartments
dpeending on the concentration of albumin or protens etc.
@Kaumudi.H he's saying that the system naturally has greater hydrostatic pressure on one side of the membrane to counteract the osmotic pressure gradient
@JohnRennie my conundrum is, what is the origin of the mysterious osmotic pressure and why is this concept required in addition to hydrostatic pressure?
 
user228700
@Kenshin I don't get that :-/
 
@Kaumudi.H Yes. Because without the pressure difference molecules of water will be continuously flowing from the solvent through the membrane into the solution.
 
user228700
Isn't that what happens?
 
@Kaumudi.H At equilibrium the net flow is zero.
 
@Kaumudi.H yes until the pressure in the compartment gets bigger
and eventually the pressure in the compartment is big enough to oppose the osmotic inflow
and thus in equillibrium, one compartment has higher "hydrostatic" pressure than the other
Does this make sense? As water flows osmitcally from compartment A to B, the pressure of compartment B gets bigger (as now contains more water)
eventually the pressure in B relative to A can halt the osmotic flow
this is equillibrium
 
user228700
6:44 AM
:-|
 
oh
 
user228700
Hang on.
 
it's simpler than you think. On the solvent side the number of solvent molecules per unit volume is higher than it is on the solution side. Molecules buzz around randomly, and the number of molecules buzzing around randomly is proportion to the density.

So when you average out the moleculat motion the flow through the membrane coming from the higher density side is greater than the flow coming from the lower density side.
 
user228700
Okay, all this screwed with whatever understanding of this concept I had. Big time. Now I don't understand anything >.<
 
@JohnRennie I think I understand it
 
6:47 AM
I recall back in my biology class, osmosis is treated as a special case of diffusion
 
So even if the pressure on the solvent side equals the pressure on the other side, this won't be enough to stop the random motion of water from diffisuing into the solvent side
 
@Kaumudi.H are you happy that in the absence of an external pressure difference there will be a net flow of solvent through the membrane?
 
thus osmotic pressure is balance between hydrostatic pressure and the randomness (entropy) of diffusion
 
user228700
@JohnRennie Nope.
 
@Kaumudi.H hmm, OK, I thought we had that one nailed.
 
6:48 AM
@JohnRennie thanks John I think I get it now
@Kaumudi.H let me try to explain ok?
Suppose we have two compartments A and B
 
user228700
One person, pls.
 
yes me first
suppose B is the "solvent" side (lower concentration of water)
 
user228700
Okay...
 
and suppose currently at time 0, hydrostatic pressure in A = hydrostatic pressure in B
and suppose there is a semi-permeable membrane separating A and B such that the solvent in B cannot pass to A
understand the set up at time 0?
Now we ask, how will the system proceed from time 0
 
user228700
@Kenshin Don't u mean solution?
 
6:51 AM
@Kaumudi.H no I mean higher concentration of solution, lower concentration of water
does this set up make sense to you?
 
user228700
What? Higher concentration of solute?
 
yes
thus lower concentration of solvent
 
user228700
Okay. That's the solution.
 
@Kaumudi.H ping me when it's my turn. I'm going to play with my computers while I'm waiting ...
 
yes
So the "solution" is coomponent B
and water is compartment A
 
user228700
6:52 AM
Okay...
 
and suppose at time 0 the hydrostatic pressure in A = hydrostatic pressure in B
now what do you think will happen from here?
even though the hydrostatic pressures are equal, this won't stop water randomly diffusing from A to B
now water could also randomly diffuse from B to A
but there will be more diffusion from A to B
why?
 
user228700
Oh, man, wait.
 
Because the concentration of water is higher in A
 
user228700
Dood, one second.
 
user228700
Right, okay, go on.
 
6:54 AM
ok
so water will diffuse from A to B randomly (even though the pressures are equal)
now what happens as you get more water building up in compartment B
this increase of volume in compartment B now means compartment B has a slightly higher hydrostatic pressure than compartment A
 
user228700
Yeah. Why? Just because of the concentration gradient?
 
@Kaumudi.H precisely
 
Somehow it never occurred to me that a probability density function might not have an average
 
user228700
@Kenshin But why? I mean, the pressures are equal.
 
@Kaumudi.H Suppose I have a glass of green water and blue water separated by a membrane (with euqla pressure)
 
6:57 AM
(even when it's otherwise "nice")
 
do you think the blue water will stay on one side and the green water on the other?
even though the pressure is equal?
of course not, they will still randomly diffuse
 
user228700
No, it won't...
 
exactly, so pressure isn't everything
just because the pressures are equal, won't stop water diffusing into compartment B
 
user228700
Entropy is everything? (Opened that can. Yup.)
 
and because compartment A has a higher concentration of water, it will diffuse more into B than B into A
@Kaumudi.H yes this diffusion is an example of entropy increasing
@Kaumudi.H so osmotic pressure is kind of like the pressure due to "entropy wanting to increase"
 
user228700
6:59 AM
@JohnRennie: Dyou have anything to add to this particular segment of this discussion about "pressure isn't everything"?
 
Osmosis is a battle between pressure and entropy
 
user228700
Wait, wait.
 
No I'll let you guys finish
 
so ultimately at equillibrium, the hydrostatic pressure in B will exceed the hydrostatic pressure in A
and we call this difference "the osmotic pressure" gradient
 

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