\documentclass{article}
\usepackage{colorspace}
\usepackage{tikz}
\definespotcolor{mygreen}{Green 355 C}{1,0,1,0}
\begin{document}\pagecolor{red!50} %to make it more visible
\begin{tikzpicture}
\fill[color=mygreen](2,0)rectangle (3,1); %fails
\fill[mygreen](3,0)rectangle (4,1);
\end{tikzpicture}
\begin{tikzpicture}
\fill[color=blue](0,0)rectangle (1,1);
\fill[blue](2,0)rectangle (3,1);
\end{tikzpicture}
\end{document}