More to the point of ZFC:
$\varnothing$ is a subset of $\{\{\varnothing\}\}$, but not an element
$\{\varnothing\}$ is an element of $\{\{\varnothing\}\}$, but not a subset
$\{\varnothing\}$ is an element and a subset of $\{\varnothing,\{\varnothing\}\}$,